Vanillin의 Polypropylene 항산화 효과 연구: Cotton Stalk Lignin 추출 천연 항산화제

Mingyu He; Han Dong; Mamatjan Yimit

Polymer(Korea), Vol.45, No.5, 717-726, September, 2021

DOI10.7317/pk.2021.45.5.717 Export Citation

Vanillin의 Polypropylene 항산화 효과 연구: Cotton Stalk Lignin 추출 천연 항산화제

Effect on the Antioxidant Capacity of Polypropylene by Vanillin: A Natural Antioxidant Extracted from Cotton Stalk Lignin

Mingyu He, Han Dong, and Mamatjan Yimit^†

Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education and Xinjiang Uyghur Autonomous Region, College of Chemical Engineering, Xinjiang University, Urumchi 830046, China

E-mail:

Vanillin (VA) was extracted from cotton stalk lignin by UV photocatalysis method using Co2+/Ni2+ as a catalyst, the yield of which was quantitative analyzed through gas chromatography-mass spectrometer and high performance liquid chromatography. The structure and thermal properties were compared between extracted and standard VA, which showed basically consistent. PP/VA materials characterized by fourier transform infrared spectroscopy were prepared by melt intercalation and subjected to 20 days thermal oxygen aging. Thermal gravimetric analysis and oxidation induction time results showed VA (0.9 wt%) could improve the thermal stability of polypropylene (PP) by 33.4 ℃ and 49.03%. Differential scanning calorimetry confirmed that VA increased the crystallinity of PP reaching to 15.70%. After 20 days aging, mechanical test showed the impact strength and breaking elongation retention of PV-3 (0.9 wt%) were 10.0% and 14.8% higher than those of PP; surface scanning electron microscopy showed that PV-3 had the most smooth surface.

Keywords:vanillin;UV photocatalysis;polypropylene;antioxidant capacity;mechanical properties

[References]

Hasegawa N, Okamoto H, Kato M, Usuki A, J. Appl. Polym. Sci., 78, 1918 (2015)
Leong YW, Bakar MBA, Ishak ZAM, Ariffin A, Polym. Degrad. Stabil., 83, 411 (2004)
Wims AM, Swarin SJ, J. Appl. Polym. Sci., 19, 1243 (2010)
Ji Y, Kim J, Bae JY, J. Appl. Polym. Sci., 102, 721 (2010)
Zhang JH, Zhang H, Wang ST, Liu MJ, Polym. Degrad. Stabil., 144, 93 (2017)
Nanni A, Messori MA, Polym. Degrad. Stabil., 149, 9 (2018)
Nanni A, Battegazzore D, Frache A, Messori M, Polym. Degrad. Stabil., 165, 49 (2019)
Zhang LB, Tan JY, Xing GY, Dong XT, Guo XQ, Bioresour. Bioprocess., 8, 10 (2021)
Malik K, Salama ES, El-Dalatony MM, Jalalah M, et al., Ind. Crop. Prod., 159, 113122 (2020)
He MY, Musajian D, Hasan G, Hou GB, Yimit M, Pol. J. Chem. Technol., 22, 78 (2020)
Hasan G, Musajan D, Hou GB, He MY, Li Y, Yimit M, Pol. J. Chem. Technol., 22, 10 (2020)
Walton KN, Mayer J, Narbad A, Phytochemistry, 63, 505 (2003)
Bagheri-Kalmarzi M, Sajedi RH, Asadollahi E, Mahmoodi NO, Hajihosseini R, Mol. Biol. Res. Commun., 1, 74 (2012)
Kansal SK, Singh M, Sud D, J. Hazard. Mater., 153(1-2), 412 (2008)
Erdocia X, Prado R, Corcuera MA, Labidi J, Biomass Bioenerg., 66, 379 (2014)
Musajian D, Hasan G, He MY, Yimit M, Pol. J. Chem. Technol., 22, 56 (2020)
Heinz LC, Pasch H, Polymer, 46(26), 12040 (2005)
Yuan JC, Silva LC, Gomes PT, Valerga B, Campos JM, Ribeiro MR, Chien JCW, Marques MM, Polymer, 46(7), 2122 (2005)
Yue XK, Zhang S, Shang NZ, Gao ST, Wang Z, Wang C, Renew. Energy, 149, 600 (2020)
Jeon WJ, Choi IH, Park JY, Lee JS, Hwang KR, Catal. Today, 37, 352 (2019)
Brisa P, Louis-Charles DM, Ricard GV, Tania G, Acs. Appl. Mater. Inter., 3, 4420 (2011)
Tang B, Yue TX, Wu JS, Dong YM, Ding Y, Wang HJ, Talanta, 64, 955 (2004)
Liu GF, Shi TS, Zhao YN, J. Mol. Struct., 412, 75 (1997)
Ando D, Nakatsubo F, Yano H, Holzforschung, 73, 493 (2019)
Karathanos VT, Mourtzinos I, Yannakopoulou K, Andrikopoulos NK, Food Chem., 101, 652 (2007)
Tai A, Sawano T, Yazama F, Ito H, BBAGen Subjects, 1810, 170 (2011)
Xue Y, Guan Y, Zheng A, Wang H, Xiao H, J. Biomat. Sci-Polym E, 23, 1115 (2012)
Viebke J, Gedde UW, Polym. Eng. Sci., 37, 896 (2010)
Fearon PK, Whiteman DJ, Billingham NC, Bigger SW, J. Appl. Polym. Sci., 79, 1986 (2015)
Zhang H, Zhen WJ, Int. J. Biol. Macromol., 139, 181 (2019)
Papadopoulos L, Klonos PA, Terzopoulou Z, Psochia Z, Bikiaris DN, Polymer, 217, 123457 (2021)
Yang L, Zhen WJ, Polym. Adv. Technol., 30, 1 (2019)
Odalanowska M, Borysiak S, Polym. Compos., 58, 478 (2021)
Feng Y, Jin X, Hay JN, J. Appl. Polym. Sci., 69, 2089 (2015)
Li J, Chen DK, Gui BZ, Gu MH, Ren J, Polym. Bull., 67(5), 775 (2011)

[1] Hasegawa N, Okamoto H, Kato M, Usuki A, J. Appl. Polym. Sci., 78, 1918 (2015)

[2] Leong YW, Bakar MBA, Ishak ZAM, Ariffin A, Polym. Degrad. Stabil., 83, 411 (2004)

[3] Wims AM, Swarin SJ, J. Appl. Polym. Sci., 19, 1243 (2010)

[4] Ji Y, Kim J, Bae JY, J. Appl. Polym. Sci., 102, 721 (2010)

[5] Zhang JH, Zhang H, Wang ST, Liu MJ, Polym. Degrad. Stabil., 144, 93 (2017)

[6] Nanni A, Messori MA, Polym. Degrad. Stabil., 149, 9 (2018)

[7] Nanni A, Battegazzore D, Frache A, Messori M, Polym. Degrad. Stabil., 165, 49 (2019)

[8] Zhang LB, Tan JY, Xing GY, Dong XT, Guo XQ, Bioresour. Bioprocess., 8, 10 (2021)

[9] Malik K, Salama ES, El-Dalatony MM, Jalalah M, et al., Ind. Crop. Prod., 159, 113122 (2020)

[10] He MY, Musajian D, Hasan G, Hou GB, Yimit M, Pol. J. Chem. Technol., 22, 78 (2020)

[11] Hasan G, Musajan D, Hou GB, He MY, Li Y, Yimit M, Pol. J. Chem. Technol., 22, 10 (2020)

[12] Walton KN, Mayer J, Narbad A, Phytochemistry, 63, 505 (2003)

[13] Bagheri-Kalmarzi M, Sajedi RH, Asadollahi E, Mahmoodi NO, Hajihosseini R, Mol. Biol. Res. Commun., 1, 74 (2012)

[14] Kansal SK, Singh M, Sud D, J. Hazard. Mater., 153(1-2), 412 (2008)

[15] Erdocia X, Prado R, Corcuera MA, Labidi J, Biomass Bioenerg., 66, 379 (2014)

[16] Musajian D, Hasan G, He MY, Yimit M, Pol. J. Chem. Technol., 22, 56 (2020)

[17] Heinz LC, Pasch H, Polymer, 46(26), 12040 (2005)

[18] Yuan JC, Silva LC, Gomes PT, Valerga B, Campos JM, Ribeiro MR, Chien JCW, Marques MM, Polymer, 46(7), 2122 (2005)

[19] Yue XK, Zhang S, Shang NZ, Gao ST, Wang Z, Wang C, Renew. Energy, 149, 600 (2020)

[20] Jeon WJ, Choi IH, Park JY, Lee JS, Hwang KR, Catal. Today, 37, 352 (2019)

[21] Brisa P, Louis-Charles DM, Ricard GV, Tania G, Acs. Appl. Mater. Inter., 3, 4420 (2011)

[22] Tang B, Yue TX, Wu JS, Dong YM, Ding Y, Wang HJ, Talanta, 64, 955 (2004)

[23] Liu GF, Shi TS, Zhao YN, J. Mol. Struct., 412, 75 (1997)

[24] Ando D, Nakatsubo F, Yano H, Holzforschung, 73, 493 (2019)

[25] Karathanos VT, Mourtzinos I, Yannakopoulou K, Andrikopoulos NK, Food Chem., 101, 652 (2007)

[26] Tai A, Sawano T, Yazama F, Ito H, BBAGen Subjects, 1810, 170 (2011)

[27] Xue Y, Guan Y, Zheng A, Wang H, Xiao H, J. Biomat. Sci-Polym E, 23, 1115 (2012)

[28] Viebke J, Gedde UW, Polym. Eng. Sci., 37, 896 (2010)

[29] Fearon PK, Whiteman DJ, Billingham NC, Bigger SW, J. Appl. Polym. Sci., 79, 1986 (2015)

[30] Zhang H, Zhen WJ, Int. J. Biol. Macromol., 139, 181 (2019)

[31] Papadopoulos L, Klonos PA, Terzopoulou Z, Psochia Z, Bikiaris DN, Polymer, 217, 123457 (2021)

[32] Yang L, Zhen WJ, Polym. Adv. Technol., 30, 1 (2019)

[33] Odalanowska M, Borysiak S, Polym. Compos., 58, 478 (2021)

[34] Feng Y, Jin X, Hay JN, J. Appl. Polym. Sci., 69, 2089 (2015)

[35] Li J, Chen DK, Gui BZ, Gu MH, Ren J, Polym. Bull., 67(5), 775 (2011)