Korean Journal of Chemical Engineering, Vol.38, No.11, 2332-2340, November, 2021
Electrical property improvement of phenolic formaldehyde resin with graphene and ionic liquid
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The ionic liquid 3-decyl-bis(1-vinyl-1H-imidazole-3-ium-bromide) (C10[VImBr]2) was synthesized and its chemical structure characterized by Fourier-transform infrared spectroscopy and 1H nuclear magnetic resonance spectroscopy. To improve the electrical conductivity of the phenolic formaldehyde (PF) resin, PF/graphene and PF/graphene/ C10[VImBr]2 composites were prepared via a melt blending and compression-curing process. The impact strength of the composites was shown to increase with the addition of increasing proportion of graphene, and with increasing proportion of C10[VImBr]2, of up to 5 wt%. In detail, the electrical conductivity of the PF/graphene composites increased significantly from 2.3 x 10-12 to 4 x 10-4 S/cm as the graphene content increased from 0 to 20 wt%. Moreover, the electrical conductivity of the PF/graphene/C10[VImBr]2 composites containing 15 wt% graphene was shown to increase from 5.6 x 10-5 to 9.2 x 10-4 S/cm as the content of C10[VImBr]2 increased from 0 to 5 wt%.
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