Bi1/2Na1/2TiO3-BiAlO3 무연 압전 세라믹스의 유전 및 전기 기계적 변형 특성에 대한 SrTiO3 첨가 효과

이상섭; 이창헌; 즈엉 짱 안; 김동혁; 김병우; 한형수; 이재신; Sang Sub Lee; Chang-Heon Lee; Trang An Duong; Dong Hyeok Kim; Byeong Woo Kim; Hyoung-Su Han; Jae-Shin Lee

Korean Journal of Materials Research, Vol.31, No.10, 562-568, October, 2021

DOI10.3740/MRSK.2021.31.10.562 Export Citation

Bi1/2Na1/2TiO3-BiAlO3 무연 압전 세라믹스의 유전 및 전기 기계적 변형 특성에 대한 SrTiO3 첨가 효과

Effects of SrTiO3-Modification on the Dielectric and Electromechanical Strain Properties of Lead-Free Bi1/2Na1/2TiO3-BiAlO3 Piezoceramics

이상섭, 이창헌, 즈엉 짱 안, 김동혁, 김병우¹, 한형수, 이재신^†

울산대학교 첨단소재공학부
¹울산대학교 전기공학부

Sang Sub Lee, Chang-Heon Lee, Trang An Duong, Dong Hyeok Kim, Byeong Woo Kim¹, Hyoung-Su Han, and Jae-Shin Lee^†

School of Material Science and Engineering, University of Ulsan, Ulsan 44610, Republic of Korea
¹Department of Electrical Engineering, University of Ulsan, Ulsan 44610, Republic of Korea

E-mail:

(Bi1/2Na1/2)TiO3 (BNT)-based ceramics are considered promising candidates for actuator application owing to their excellent electromechanical strain properties However, to obtain large strain properties, there remain several issues such as thermal stability and high operating fields. Therefore, this study investigates a reduction of operating field in (0.98-x)Bi1/2Na1/ 2TiO3-0.02 BiAlO3-xSrTiO3 (BNT-2BA-100xST, x = 0.20, 0.21, 0.22, 0.23, and 0.24) via analyses of the microstructure, crystal structure, dielectric, polarization, ferroelectric and electromechanical strain properties. The average grain size of BNT-2BA- 100xST ceramics decreases with increasing ST content. Results of polarization and electromechanical strain properties indicate that a ferroelectric to relaxor state transition is induced by ST modification. As a consequence, a large electromechanical strain of 592 pm/V is obtained at a relatively low electric field of 4 kV/mm in 22 mol% ST-modified BNT-2BA ceramics. We believe that the materials synthesized in this study are promising candidates for actuator applications.

Keywords:lead-free;piezoceramics;relaxor;ferroelectric

[References]

Koruza J, Bell AJ, Fromling T, Webber KG, Wang K, Rodel J, J. Materiomics, 4, 13 (2018)
Jo W, Dittmer R, Acosta M, Zang J, Groh C, Sapper E, Wang K, Rodel J, J. Electroceramics, 29, 71 (2012)
Rodel J, Webber KG, Dittmer R, Jo W, Kimura M, Damjanovic D, J. European Ceram. Soc., 35, 1659 (2015)
Zheng T, Wu J, Xiao D, Zhu J, Progr. Mater. Sci., 98, 552 (2018)
Damjanovic D, Klein N, Li J, Porokhonskyy V, Funct. Mater. Lett., 3, 5 (2010)
Wu L, Shen B, Hu QR, Chen J, Wang YP, Xia YD, Yin J, Liu ZG, J. Am. Ceram. Soc., 100(10), 4670 (2017)
Wu J, J. Appl. Phys., 127, 190901 (2020)
Han HS, Duong TA, Ahn CW, Jo W, Lee JS, Ceramist, 23, 89 (2020)
Jeong GH, Lee SS, Ahn CW, Han HS, Lee JS, J. Korean Inst. Electr. Electron. Mater. Eng., 33, 337 (2020)
Hinterstein M, Knapp M, Holzel M, Jo W, Cervellino A, Ehrenberg H, Fuess H, J. Appl. Crystallogr., 43, 1314 (2010)
Ahn CW, Hong CW, Choi BY, et al., J. Korean Phys. Soc., 68, 1481 (2016)
Song G, Zhang F, Liu F, Liu Z, Li Y, J. Am. Ceram. Soc., 104, 4049 (2021)
Zylberberg J, Beilk Z, Muromachi ET, Ye ZG, Chem. Mater., 19, 6385 (2007)
Ullah A, Ahm CW, Hussain A, Kim IW, Hwang HI, Cho NK, Solid State Commun., 150, 1145 (2010)
Zylberberg J, Belik AA, Takayama-Muromachi E, Ye ZG, Chem. Mater., 19, 6385 (2007)
Baettig P, Schelle CF, Lesar R, Waghmare UV, Spaldin NA, Chem. Mater., 17, 1376 (2005)
Ullah A, Ahn CW, Hussain A, Lee SY, Kim IW, J. Am. Ceram. Soc., 94(11), 3915 (2011)
Nugyen HTK, Duong TA, Erkinov F, Ahn CW, Kim BW, Han HS, Lee JS, J. Electron. Mater., 49, 6677 (2020)
Hoang AP, Steiner S, Yang F, Li L, Sinclair D, Fromling T, J. European Ceram. Soc., 41, 2587 (2021)
Nguyen HTK, Duong TA, Erkinov F, Kang HW, Kim BW, Ahn CW, Han HS, Lee JS, J. Korean. Ceram. Soc., 57, 570 (2020)
Tong XY, Du ZZ, Yang YT, Song MW, Zhou JJ, Zhang HB, Guan CL, Liu H, Fang JZ, J. Alloy. Compd., 857, 15 (2021)
Zhu Y, Zhang Y, Xie B, Fan P, Marwat MA, Ma W, Wang C, Yang B, Xiao J, Zhang H, Ceram. Int., 44, 7851 (2018)
KraussW, Schutz D, Mautner FA, Feteria A, Reichmann K, J. European Ceram. Soc., 30, 1827 (2010)
Li HL, Liu Q, Zhou JJ, Wang K, Li JF, Liu H, Fang JZ, J. European Ceram. Soc., 36, 2849 (2016)
Wang K, Hussain A, Jo W, Rodel J, J. Am. Ceram. Soc., 95(7), 2241 (2012)
Shen K, Liu Y, Wang J, Yu Z, Sun X, Lyu Y, Mater. Res. Express, 6, 115218 (2019)
Yu H, Ye ZG, Appl. Phys. Lett., 93, 112902 (2008)
Ullah A, Ahn CW, Hussain A, Lee SY, Lee HJ, Kim IW, Curr. Appl. Phys., 10(4), 1174 (2010)
Ullah A, Lee SY, Lee HJ, Kim IW, Ahn CW, Hwang HI, Hussain A, Lee JS, J. Korean. Phys. Soc., 57, 1102 (2010)
Jo S, Hong CH, Kim DS, Kang HW, Ahn CW, Lee HG, Hahm S, Jo W, Han SH, Sens. Actuators A-Phys., 258, 201 (2017)
Dinh TH, Han HS, Lee JS, Mater. Lett., 258, 126793 (2020)

[1] Koruza J, Bell AJ, Fromling T, Webber KG, Wang K, Rodel J, J. Materiomics, 4, 13 (2018)

[2] Jo W, Dittmer R, Acosta M, Zang J, Groh C, Sapper E, Wang K, Rodel J, J. Electroceramics, 29, 71 (2012)

[3] Rodel J, Webber KG, Dittmer R, Jo W, Kimura M, Damjanovic D, J. European Ceram. Soc., 35, 1659 (2015)

[4] Zheng T, Wu J, Xiao D, Zhu J, Progr. Mater. Sci., 98, 552 (2018)

[5] Damjanovic D, Klein N, Li J, Porokhonskyy V, Funct. Mater. Lett., 3, 5 (2010)

[6] Wu L, Shen B, Hu QR, Chen J, Wang YP, Xia YD, Yin J, Liu ZG, J. Am. Ceram. Soc., 100(10), 4670 (2017)

[7] Wu J, J. Appl. Phys., 127, 190901 (2020)

[8] Han HS, Duong TA, Ahn CW, Jo W, Lee JS, Ceramist, 23, 89 (2020)

[9] Jeong GH, Lee SS, Ahn CW, Han HS, Lee JS, J. Korean Inst. Electr. Electron. Mater. Eng., 33, 337 (2020)

[10] Hinterstein M, Knapp M, Holzel M, Jo W, Cervellino A, Ehrenberg H, Fuess H, J. Appl. Crystallogr., 43, 1314 (2010)

[11] Ahn CW, Hong CW, Choi BY, et al., J. Korean Phys. Soc., 68, 1481 (2016)

[12] Song G, Zhang F, Liu F, Liu Z, Li Y, J. Am. Ceram. Soc., 104, 4049 (2021)

[13] Zylberberg J, Beilk Z, Muromachi ET, Ye ZG, Chem. Mater., 19, 6385 (2007)

[14] Ullah A, Ahm CW, Hussain A, Kim IW, Hwang HI, Cho NK, Solid State Commun., 150, 1145 (2010)

[15] Zylberberg J, Belik AA, Takayama-Muromachi E, Ye ZG, Chem. Mater., 19, 6385 (2007)

[16] Baettig P, Schelle CF, Lesar R, Waghmare UV, Spaldin NA, Chem. Mater., 17, 1376 (2005)

[17] Ullah A, Ahn CW, Hussain A, Lee SY, Kim IW, J. Am. Ceram. Soc., 94(11), 3915 (2011)

[18] Nugyen HTK, Duong TA, Erkinov F, Ahn CW, Kim BW, Han HS, Lee JS, J. Electron. Mater., 49, 6677 (2020)

[19] Hoang AP, Steiner S, Yang F, Li L, Sinclair D, Fromling T, J. European Ceram. Soc., 41, 2587 (2021)

[20] Nguyen HTK, Duong TA, Erkinov F, Kang HW, Kim BW, Ahn CW, Han HS, Lee JS, J. Korean. Ceram. Soc., 57, 570 (2020)

[21] Tong XY, Du ZZ, Yang YT, Song MW, Zhou JJ, Zhang HB, Guan CL, Liu H, Fang JZ, J. Alloy. Compd., 857, 15 (2021)

[22] Zhu Y, Zhang Y, Xie B, Fan P, Marwat MA, Ma W, Wang C, Yang B, Xiao J, Zhang H, Ceram. Int., 44, 7851 (2018)

[23] KraussW, Schutz D, Mautner FA, Feteria A, Reichmann K, J. European Ceram. Soc., 30, 1827 (2010)

[24] Li HL, Liu Q, Zhou JJ, Wang K, Li JF, Liu H, Fang JZ, J. European Ceram. Soc., 36, 2849 (2016)

[25] Wang K, Hussain A, Jo W, Rodel J, J. Am. Ceram. Soc., 95(7), 2241 (2012)

[26] Shen K, Liu Y, Wang J, Yu Z, Sun X, Lyu Y, Mater. Res. Express, 6, 115218 (2019)

[27] Yu H, Ye ZG, Appl. Phys. Lett., 93, 112902 (2008)

[28] Ullah A, Ahn CW, Hussain A, Lee SY, Lee HJ, Kim IW, Curr. Appl. Phys., 10(4), 1174 (2010)

[29] Ullah A, Lee SY, Lee HJ, Kim IW, Ahn CW, Hwang HI, Hussain A, Lee JS, J. Korean. Phys. Soc., 57, 1102 (2010)

[30] Jo S, Hong CH, Kim DS, Kang HW, Ahn CW, Lee HG, Hahm S, Jo W, Han SH, Sens. Actuators A-Phys., 258, 201 (2017)

[31] Dinh TH, Han HS, Lee JS, Mater. Lett., 258, 126793 (2020)