화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.29, No.10, 649-664, October, 2021
DOI10.1007/s13233-021-9088-2  Export Citation
A Brief Review of Self-Healing Polyurethane Based on Dynamic Chemistry
Won-Ji Lee, Hyeon-Gyeong Oh, and Sang-Ho Cha†
  • Department of Chemical Engineering, Kyonggi University, 154-42, Gwanggyosan-ro, Yeongtong-gu, Suwon, Gyeonggi 16227, Korea
E-mail:
Self-healing synthetic polymers have attracted considerable scientific attention owing to their excellent durability and extended lifetimes. Among the categories of extrinsic and intrinsic self-healing, the intrinsic process is being focused on recently because it can realize rapid and reversible self-healing abilities and repeatability through dynamic chemical bonds. Intrinsic self-healing was categorized into two types: reversible covalent and non-covalent bonding, which include reversible cycloaddition reactions, exchange reactions, hydrogen interactions, and metal-ligand coordination interactions. This review focuses on recent studies about self-healing polyurethanes, which are known to exhibit remarkably high elasticity, high tensile strength, low-temperature resistance, and corrosion resistance. The various methods used for realizing efficient self-healing polyurethanes are also explored.
Keywords:self-healing polyurethane;reversible covalent bonds;reversible non-covalent bonds
  1. Li Z, Zhang RW, Moon KS, Liu Y, Hansen K, Le TR, Wong CP, Adv. Funct. Mater., 23(11), 1459 (2013)
  2. Jiang S, Li Q, Zhao Y, Wang J, Kang M, Compos. Sci. Technol., 110, 87 (2015)
  3. Savas LA, Deniz TK, Tayfun U, Dogan M, Polym. Degrad. Stabil., 135, 121 (2017)
  4. Pokharel P, Choi S, Compos. Part A: Appl. Sci. Manufact., 69, 168 (2015)
  5. Jing Q, Liu W, Pan Y, Silberschmidt VV, Li L, Dong Z, Mater. Des., 85, 808 (2015)
  6. Diesendruck CE, Sottos NR, Moore JS, White SR, Angew. Chem.-Int. Edit., 54, 10428 (2015)
  7. Dahlke J, Zechel S, Hager MD, Schubert US, Adv. Mater. Interfaces, 5, 180005 (2018)
  8. Dello Iacono S, Martone A, Pastore A, Filippone G, Acierno D, Zarrelli M, Giordano M, Amendola E, Polym. Eng. Sci., 57(7), 674 (2017)
  9. Feng LB, Yu ZY, Bian YH, Lu JS, Shi XT, Chai CS, Polymer, 124, 48 (2017)
  10. Li G, Xiao P, Hou S, Huang Y, Carbon, 147, 398 (2019)
  11. Turkenburg DH, Durant Y, Fischer HR, Prog. Org. Coat., 111, 38 (2017)
  12. Fortunato G, Tatsi E, Rigatelli B, Turri S, Griffini G, Macromol. Mater. Eng., 305, 190065 (2020)
  13. Zhu Y, Cao K, Chen M, Wu L, ACS Appl. Mater. Interfaces, 11, 33314 (2019)
  14. Zhu Y, Chen M, Wu L, Chem. Eng. J., 422, 130034 (2021)
  15. Abdallh M, Hearn MT, Simon GP, Saito K, Polym. Chem., 8, 5875 (2017)
  16. Li W, Ni XM Zhang X, Lei Y, Guo J, Jin J, You B, ACS Appl. Mater. Interfaces, 12, 48101 (2020)
  17. An Q, Wessely ID, Matt Y, Hassan Z, Brase S, Tsotsalas M, Polym. Chem., 10, 672 (2019)
  18. Zhang MQ, Rong MZ, J. Mater. Chem. A, 2, 6558 (2014)
  19. Zhang ZP, Rong MZ, Zhang MQ, Polymer, 55(16), 3936 (2014)
  20. Blaiszik BJ, Kramer SL, Olugebefola SC, Moore JS, Sottos NR, White SR, Annu. Rev. Mater. Res., 40, 179 (2010)
  21. Zhao Y, Zhang W, Liao LP, Wang SJ, Li WJ, Appl. Surf. Sci., 258(6), 1915 (2012)
  22. Gergely RC, Cruz WAS, Krull BP, Pruitt EL, Wang J, Sottos NR, White SR, Adv. Funct. Mater., 28, 170419 (2018)
  23. Kim SR, Getachew BA, Kim JH, J. Membr. Sci., 531, 94 (2017)
  24. Lehn JM, Prog. Polym. Sci, 30, 814 (2005)
  25. Zheng N, Xu Y, Zhao Q, Xie T, Chem. Rev., 121(3), 1716 (2021)
  26. Willocq B, Odent J, Dubois P, Raquez JM, RSC Adv., 10, 13766 (2020)
  27. Kazemi-Lari MA, Malakooti MH, Sodano HA, Smart Mater. Struct., 26, 055003 (2017)
  28. Chen W, Zhou Y, Li Y, Sun J, Pan X, Yu Q, Zhou N, Zhang Z, Zhu X, Polym. Chem., 7, 6789 (2016)
  29. Chen SL, Wang FF, Peng YJ, Chen TH, Wu Q, Sun PC, Macromol. Rapid Commun., 36(18), 1687 (2015)
  30. Aizpurua J, Martin L, Fernandez M, Gonzalez A, Irusta L, Prog. Org. Coat., 139, 105460 (2020)
  31. Kim JW, Lee DH, Jeon HJ, Jang SI, Cho HM, Kim Y, Appl. Surf. Sci., 429, 128 (2018)
  32. Irusta L, Fernandez-Berridi MJ, Aizpurua J, J. Appl. Polym. Sci, 134 (2017)
  33. Zhang RC, Yu S, Chen SL, Wu Q, Chen TH, Sun PC, Li BH, Ding DT, J. Phys. Chem. B, 118(4), 1126 (2014)
  34. Liu X, Zhan Y, Zhao C, Su Y, Ge Z, Luo Y, Polymers, 12, 1513 (2020)
  35. Loeffler N, Kopel T, Kim GT, Passerini S, J. Electrochem. Soc., 162(14), A2692 (2015)
  36. Slobodian P, Riha P, Benlikaya R, Svoboda P, Petras D, IEEE Sens. J., 13, 4045 (2013)
  37. Li M, Li H, Zhong W, Zhao Q, Wang D, ACS Appl. Mater. Interfaces, 6, 1313 (2014)
  38. Tai ZX, Yan XB, Xue QJ, J. Power Sources, 213, 350 (2012)
  39. Bahrami S, Solouk A, Mirzadeh H, Seifalian AM, Compos. Part B: Eng., 168, 421 (2019)
  40. Wu J, Wang H, Su Z, Zhang M, Hu X, Wang Y, Wang Z, Zhong B, Zhou W, Liu J, ACS Appl. Mater. Interfaces, 9, 38745 (2017)
  41. Zhang S, Liu H, Yang S, Shi X, Zhang D, Shan C, Mi L, Liu C, Shen C, Guo Z, ACS Appl. Mater. Interfaces, 11, 10922 (2019)
  42. Lee SH, Shin SR, Lee DS, Mater. Des., 172, 107774 (2019)
  43. Kuhl N, Bode S, Bose RK, Vitz J, Seifert A, Hoeppener S, Garcia SJ, Spange S, van der Zwaag S, Hager MD, Schubert US, Adv. Funct. Mater., 25(22), 3295 (2015)
  44. Fan LF, Rong MZ, Zhang MQ, Chen XD, ACS Appl. Mater. Interfaces, 10, 38538 (2018)
  45. Xiang HP, Yin JF, Lin GH, Liu XX, Rong MZ, Zhang MQ, Chem. Eng. J., 358, 878 (2019)
  46. Ghosh B, Urban MW, Science, 323, 1458 (2009)
  47. Ghosh B, Chellappan KV, Urban MW, J. Mater. Chem., 21, 14473 (2011)
  48. Ghosh B, Chellappan KV, Urban MW, J. Mater. Chem., 22, 16104 (2012)
  49. Yang Y, Urban MW, Angew. Chem.-Int. Edit., 126, 12338 (2014)
  50. Yuan CE, Rong MZ, Zhang MQ, Zhang ZP, Yuan YC, Chem. Mater., 23, 5076 (2011)
  51. Yuan CE, Rong MZ, Zhang MQ, Polymer, 55(7), 1782 (2014)
  52. Zhang ZP, Rong MZ, Zhang MQ, Polym. Chem., 4, 4648 (2013)
  53. Imato K, Nishihara M, Kanehara T, Amamoto Y, Takahara A, Otsuka H, Angew. Chem.-Int. Edit., 124, 1164 (2012)
  54. Kuang X, Liu GM, Dong X, Liu XG, Xu JJ, Wang DJ, J. Polym. Sci. A: Polym. Chem., 53(18), 2094 (2015)
  55. Urdl K, Weiss S, Christofl P, Kandelbauer A, Muller U, Kern W, Eur. Polym. J., 127, 109601 (2020)
  56. Fang Y, Du X, Jiang Y, Du Z, Pan P, Cheng X, Wang H, ACS Sustain. Chem. Eng., 6, 14490 (2018)
  57. Wang Z, Zhou J, Liang H, Ye S, Zou J, Yang H, Prog. Org. Coat., 149, 105943 (2020)
  58. Byun KS, Choi WJ, Lee HY, Sim MJ, Cha SH, Lee JC, RSC Adv., 8, 39432 (2018)
  59. Truong TT, Thai SH, Nguyen HT, Phung DTT, Nguyen LT, Pham HQ, Nguyen LTT, Chem. Mater., 31, 2347 (2019)
  60. Lee HY, Cha SH, Macromol. Res., 25(6), 640 (2017)
  61. Lee WJ, Cha SH, Polymers, 12, 603 (2020)
  62. Wong CS, Hassan NI, Su’ait MS, Serra MAP, Gonzalez JAM, Granda LA, Badri KH, Ind. Crop. Prod., 140, 111613 (2019)
  63. Li R, Chen J, Zhou T, Pei J, Constr. Build. Mater., 105, 336 (2016)
  64. Ling J, Rong MZ, Zhang MQ, J. Mater. Chem., 21, 18373 (2011)
  65. Wang Y, Liu Q, Li JH, Ling L, Zhang GP, Sun R, Wong CP, Polymer, 172, 187 (2019)
  66. Xu Y, Chen D, Macromol. Chem. Phys., 217, 1191 (2016)
  67. Zhou F, Guo Z, Wang W, Lei X, Zhang B, Zhang H, Zhang Q, Compos. Sci. Technol., 167, 79 (2018)
  68. Nevejans S, Ballard N, Fernandez M, Reck B, Asua JM, Polymer, 166, 229 (2019)
  69. Nevejans S, Ballard N, Miranda JI, Reck B, Asua JM, Phys. Chem. Chem. Phys., 18, 27577 (2016)
  70. Wan T, Chen DJ, J. Mater. Sci., 52(1), 197 (2017)
  71. Xu YR, Chen DJ, J. Mater. Sci., 53(14), 10582 (2018)
  72. Azcune I, Odriozola I, Eur. Polym. J., 84, 147 (0216)
  73. Chang K, Jia H, Gu SY, Eur. Polym. J., 112, 822 (2019)
  74. Brunsveld L, Folmer BJB, Meijer EW, Sijbesma RP, Chem. Rev., 101(12), 4071 (2001)
  75. Lehn JM, Science, 260, 1762 (1993)
  76. Chen J, Peng Q, Thundat T, Zeng H, Chem. Mater., 31, 4553 (2019)
  77. Liang Z, Huang D, Zhao L, Nie Y, Zhou Z, Hao T, Li S, J. Inorg. Organomet. Polym. Mater., 31, 683 (2021)
  78. Trinh NH, Jaafar M, Viet CX, Zubir SA, Materials Research Express, 7, 025704 (2020)
  79. Zhu K, Song Q, Chen H, Hu P, J. Appl. Polym. Sci., 135, 45929 (2018)
  80. Yuan J, Fang X, Zhang L, Hong G, Lin Y, Zheng Q, Xu Y, Ruan W, Xia H, J. Mater. Chem., 22, 11515 (2012)
  81. Faghihnejad A, Feldman KE, Yu J, Tirrell MV, Israelachvili JN, Hawker CJ, Kramer EJ, Zeng HB, Adv. Funct. Mater., 24(16), 2322 (2014)
  82. Cao J, Lu C, Zhuang J, Liu M, Zhang X, Yu Y, Tao Q, Angew. Chem.-Int. Edit., 56, 8795 (2017)
  83. Fan CJ, Huang ZC, Li B, Xiao WX, Zheng E, Yang KK, Wang YZ, Sci. China Mater, 62 (2019)
  84. Hu J, Mo R, Jiang X, Sheng X, Zhang X, Polymer, 183, 121912 (2019)
  85. Xu S, Sheng D, Zhou Y, Wu H, Xie H, Tian X, Sun Y, Liu X, Yang Y, New J. Chem., 44, 7395 (2020)
  86. Mozhdehi D, Ayala S, Cromwell OR, Guan ZB, J. Am. Chem. Soc., 136(46), 16128 (2014)
  87. Shi L, Ding P, Wang Y, Zhang Y, Ossipov D, Hilborn J, Macromol. Rapid Commun., 40, 180083 (2019)
  88. Wang Z, Xie C, Yu C, Fei G, Wang Z, Xia H, Macromol. Rapid Commun., 39, 170067 (2018)
  89. Chen PK, Li QC, Grindy S, Holten-Andersen N, J. Am. Chem. Soc., 137(36), 11590 (2015)
  90. McConnell AJ, Wood CS, Neelakandan PP, Nitschke JR, Chem. Rev., 115(15), 7729 (2015)
  91. Das M, Pal S, Naskar K, Express Polym. Lett., 14 (2020)
  92. Li C, Tan J, Guan Z, Zhang Q, Macromol. Rapid Commun., 40, 180090 (2019)
  93. Gai G, Liu L, Li CH, Bose RK, Li D, Guo N, Kong B, ChemPlus-Chem, 84, 432 (2019)
  94. Xu S, Sheng D, Liu X, Ji F, Zhou Y, Dong L, Wu H, Yang Y, Polym. Int., 68, 1084 (2019)
  95. Sinawang G, Osaki M, Takashima Y, Yamaguchi H, Harada A, Chem. Commun., 56, 4381 (2020)
  96. Xiong H, Li Y, Ye H, Huang G, Zhou D, Huang Y, J. Mater. Chem. B, 8, 10309 (2020)
  97. Elsabahy M, Wooley KL, J. Polym. Sci. A: Polym. Chem., 50(10), 1869 (2012)
  98. Lehn JM, Accounts Chem. Res., 11, 49 (1978)
  99. Nomimura S, Osaki M, Park J, Ikura R, Takashima Y, Yamaguchi H, Harada A, Macromolecules, 52(7), 2659 (2019)
  100. Jin C, Sinawang G, Osaki M, Zheng Y, Yamaguchi H, Harada A, Takashima Y, Polymers, 12, 1393 (2020)
  101. Sugane K, Shibata M, Polymer, 221, 123629 (2021)
  102. Zhang E, Shi J, Xiao L, Zhang Q, Lu M, Nan B, Wu K, Lu M, Polym. Chem., 12, 831 (2021)
  103. Xiao L, Shi J, Wu K, Lu M, React. Funct. Polym., 148, 104482 (2020)
  104. Duan N, Sun Z, Ren Y, Liu Z, Liu L, Yan F, Polym. Chem., 11, 867 (2020)