Journal of Industrial and Engineering Chemistry, Vol.105, 337-351, January, 2022
Long-term catalytic durability in Z-scheme CdS@ 1T-WS2 heterojunction materials
E-mail:,
This study aimed to improve the long-term durability of CdS catalysts by reducing the deterioration of catalytic activity caused by photocorrosion. An ultrathin 1T-WS2 2D nanosheet was introduced to enclose the CdS nanorods. The crystal defects in the wrapped CdS particles were reduced, and the WS2 sheet became thinner in the junction particle. The 2CdS@1WS2 junction particle exhibited the slowest decay time of the photoluminescence curve, and the photocurrent density increased by more than 3.5-fold in the junction particle than the single CdS particle. Eventually, the optimized 2CdS@1WS2 catalyst exhibited a high rate of H2 production of ≈3935 μmol g-1h-1 under simulated solar light irradiation with a quantum efficiency of 50%. Although the recycling experiment was repeated over 10 times using the 2CdS@1WS2 junction particle, the produced hydrogen amount did not decrease. This result is because CdS nanorods wrapped stably by the ultrathin WS2 nanosheets, which suppressed the photocorrosion of CdS, and furthermore, the 1T phase WS2 rapidly attracted photogenerated electrons from CdS, facilitating charge separation and inhibiting their recombination, thereby improving the catalyst activity. Finally, it was revealed that an effective Z-scheme charge transfer mechanism in the CdS@1T-WS2 junction particle follows during water splitting.
Keywords:Long-term durability;Charge carrier separation;1T-WS2 2D nanosheet;Z-scheme charge transfer
- Muradov N, Int. J. Hydrog. Energy, 42(20), 14058 (2017)
- Kim JH, Hansora D, Sharma P, Jang JW, Lee JS, Chem. Soc. Rev., 48, 1908 (2019)
- Li Z, Guo P, Han R, Sun H, Energy Explor. Exploit., 37, 5 (2019)
- Tarnay DS, Int. J. Hydrog. Energy, 10, 577 (1985)
- Islam AKMK, Dunlop PSM, Hewitt NJ, Lenihan R, Brandoni C, Clean Technol., 3, 156 (2021)
- Eidsvag H, Bentouba S, Vajeeston P, Yohi S, Velauthapillai D, Molecules, 26, 1687 (2021)
- Raizada P, Kumar A, Hasija V, Singh P, Thakur VK, Khan AAP, J. Ind. Eng. Chem., 93, 1 (2021)
- He H, Wu B, Yang C, Int. J. Environ. Sci. Technol., 16, 7275 (2019)
- Li Z, Meng X, Zhang Z, J. Photochem. Photobiol. C: Photochem. Rev., 35, 39 (2018).
- Li W, Lin Z, Yang G, Nanoscale, 9, 18290 (2017)
- Chava RK, Do JY, Kang M, J. Mater. Chem. A, 7, 13614 (2019)
- Park BH, Lee JH, Park HR, Do JY, Kim YS, Chava RK, Kang MS, J. Ind. Eng. Chem., 91, 149 (2020)
- Lin L, Huang S, Zhu Y, Du B, Zhang Z, Chen C, Wang X, Zhang N, Dalton Trans., 48, 2715 (2019)
- Reddy NL, Rao VN, Kumari MM, Sathish M, Venkatakrishnan SM, Int. J. Hydrog. Energy, 43(49), 22315 (2018)
- Chen J, Wu XJ, Yin L, Li B, Hong X, Fan Z, Chen B, Xue C, Zhang h, Angew. Chem.-Int. Edit., 54, 1210 (2015)
- Xu D, Xu P, Zhu Y, Peng W, Li Y, Zhang G, Zhang F, Mallouk TE, Fan X, ACS Appl. Mater. Interf., 10, 2810 (2018)
- Zhang K, Fujitsuka M, Du Y, Majima T, ACS Appl. Mater. Interf., 10, 20458 (2018)
- Gopannagari M, Kumar DP, Reddy DA, Hong S, Song MI, Kim TK, J. Catal., 351, 153 (2017)
- Eftekhari A, J. Mater. Chem. A, 5, 18299 (2017)
- Jian J, Xu Y, Yang X, Liu W, Fu M, Yu H, Xu F, Feng F, Jia L, Friedrich D, van de Krol R, Wang H, Nat. Commun., 10, 2609 (2019)
- Pawar AS, Masikane SC, Mlowe S, Garje SS, Revaprasadu N, Eur. J. Inorg. Chem., 2015, 366 (2016)
- Zhang X, Wang J, Xu H, Tan H, Ye X, Nanomaterials, 9, 840 (2019)
- Adigilli HK, Padya B, Venkatesh L, Chakravadhanula VSK, Pandey AK, Joardar J, Phys. Chem. Chem. Phys., 21, 25139 (2019)
- He Q, Wang L, Yin K, Luo S, Nanoscale Res. Lett., 13, 167 (2018)
- Wang F, Kinloch IA, Wolverson D, Tenne R, Zak A, O’Connell E, Bangert U, Young RJ, 2D Mater., 4 (2016)
- Chen YW, Shie MY, Hsiao CH, Liang YC, Wang B, Chen IWP, npj 2D Mater. Appl., 34, 1 (2020)
- Baibarac M, Nila A, Baltog I, OSA, 6, 1881 (2016)
- Yadav AN, Kumar R, Jaiswal RK, Singh AK, Kumar P, Singh K, Mater. Res. Exp., 6 (2019)
- Dzhagan V, Milekhin AG, Ya M. Valakh, Pedetti S, Tessier M, Dubertret B, Zahn DRT, Nanoscale, 8, 17204 (2016)
- Rahmanian E, Mayorga-Martinez CC, Malekfar R, Luxa J, Sofer Z, Pumera M, ACS Appl. Nano Mater., 1, 7006 (2018)
- Gong Y, Zhang X, Yang T, Huang W, Liu H, Liu H, Zheng B, Li D, Zhu X, Hu W, Pan A, Nanotechnology, 30 (2019)
- Kumar DS, Hong S, Reedy DA, Kim TK, J. Mater. Chem., 4, 18551 (2016)
- Sokolikova MS, Mattevi C, Chem. Soc. Rev., 49, 3952 (2020)
- Li H, Jia X, Zhang Q, Wang X, Chem, 4, 1510 (2018)
- Liu Z, Li N, Su C, Zhao H, Xu L, Yin Z, Li J, Du Y, Nano Energy, 50, 176 (2018)
- He Q, Wang L, Yin K, Luo S, Nanoscale Res. Lett., 13, 167 (2018)
- Muh’d IB, Talib ZA, Akbari-Sharbaf A, Results Phys., 7, 1883 (2017)
- Zhang YC, Afzal N, Pan L, Zhang X, Zou JJ, Adv. Sci., 6(10), 190005 (2019)
- Zhang L, Han Z, Wang W, Li X, Su Y, Jiang D, Lei X, Sun S, Chem. A Eur. J., 21, 18089 (2015)
- Sotomayor FJ, Cychosz KA, Thommes M, Accounts Chem. Res., 3(2), 34 (2018)
- Bernard P, Stelmachowski P, Bros P, Makowski W, Kotarba A, J. Chem. Edu., 98, 935 (2021)
- Wu CY, Tu KJ, Deng JP, Lo YS, Wu CH, Materials, 10(5), 566 (2017)
- Pan L, Zhang X, Wang L, Zou JJ, Mater. Lett., 160, 576 (2015)
- Hassanien AH, Akl AA, J. Alloy. Compd., 648, 280 (2015)
- Makuła P, Pacia M, Macyk W, Accounts Chem. Res., 9, 6814 (2018)
- Hankin A, Bedoya-Lora FE, Alexander JC, Regoutz A, Kelsall GH, J. Mater. Chem. A, 7, 26162 (2019)
- Zhang F, Lu Y, Schulman DS, Zhang T, Fujisawa K, Lin Z, Lei Y, Elias AL, Das S, Sinnott SB, Terrones M, Sci. Adv., 5, eaav50 (2019)
- Zhao X, Wang T, Peng Y, Dai X, J. Alloy. Compd., 649, 357 (2015)
- Yin XL, He GY, Sun B, Jiang WJ, Xue DJ, Xia AD, Wan LJ, Hu JS, Nano Energy, 8, 319 (2016)
- Park H, Kim S, Kim T, Kim Y, Joo SW, Kang M, J. Clean Prod., 319 (2021)
- Arab S, Yao M, Zhou C, Dapkus PD, Cronin SB, Appl. Phys. Lett., 108 (2016)
- Lin KT, Chen HL, Lai YS, Liu YL, Tseng YC, Lin CH, ACS Appl. Mater. Interf., 6, 19866 (2014)
- Du JM, Wang HM, Yang MK, Zhang FF, Wu HR, Cheng XC, Yuan SJ, Zhang B, Li KD, Wang YN, Lee H, Int. J. Hydrog. Energy, 43(19), 9307 (2018)
- Kumaravel V, Imam MD, Badreldin A, Chava RK, Do JY, Kang M, Abdel-Wahab A, Catalysts, 9, 276 (2019)
- Liang S, Zhou Z, Wu X, Zhu S, Bi J, Zhou L, Liu M, Wu L, Molecules, 21, 213 (2016)
- Park H, Son N, Park BH, Joo SW, Kang M, Appl. Surf. Sci., 541 (2021)
- Chava RK, Son N, Kim YS, Kang M, Inorg. Chem. Front., 7, 2818 (2020)