화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.105, 435-445, January, 2022
DOI10.1016/j.jiec.2021.10.005  Export Citation
Fabrication of MOF-808(Zr) with abundant defects by cleaving ZrAO bond for oxidative desulfurization of fuel oil
Yulong Gu, Hongsi Luo, Wei Xu1, Wei Zhou2, and Yinyong Sun†
  • MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China
  • 1State Key Lab of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China
  • 2Key Laboratory of Functional Inorganic Material Chemistry, Heilongjiang University, Ministry of Education, Harbin 150080, China
E-mail:
Creation of defects in metal.organic frameworks (MOFs) has been demonstrated to be of significance for many potential applications. MOF-808(Zr), as an important member of MOFs, has attracted extensive attention due to its advantages such as high stability, large surface area and pore size. Therefore, the development of defective MOF-808(Zr) is of great interest. In this contribution, we report that MOF-808(Zr) with abundant defects can be fabricated by the fracture of partial Zr-O bonds in its structure by the treatment of NH4HCO3 solution. During the treatment, the effect of NH4HCO3 concentration and treatment time on the structural properties of MOF-808(Zr) was investigated. The catalytic performance of obtained materials was evaluated by the oxidative desulfurization reaction of dibenzothiophene. The results revealed that MOF-808(Zr) obtained under the conditions of 0.08 M NH4HCO3 and treatment time of 10 min exhibited superior catalytic activity (124.8 mmol/h/g) at 60 °C due to the formation of rich defect sites in MOF-808(Zr).
Keywords:MOF-808(Zr);Defect sites;Oxidative desulfurization;Dibenzothiophene;Fuel oil
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