화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.105, 549-562, January, 2022
Multifunctional, flexible and mechanically resilient porous polyurea/graphene composite film
E-mail:, ,
In this study, a porous polyurea/graphene platelet (GnP) composite film with high flexibility and multifunctionality was developed and investigated for strain sensing and energy storage applications. Morphology and mechanical properties were studied; tensile strength and Young’s modulus were enhanced by 132% and 900%, respectively at 5 wt% GnPs. The polyurea/GnP film exhibited high sensitivity to various strains. namely, tension, compression, bending and twisting. In tensile strain, gauge factor was 1.86 and 6.26 within strain ranges of 0-30% and 30-60%, respectively. Interestingly, the film showed piezoresistive and capacitive-type strain sensor under compression load; a 33% increase in relative resistance with response time of 108 millisecond; and 22% increase in relative capacitance with response time of 92 millisecond when load of 5 kPa was applied. Furthermore, the strain sensor showed high durability and reliability over 20,000 cycles. The developed polyurea/GnP film showed a stable capacitive performance over 20,000 charge.discharge cycles. This work provides important insights for the potential of polyurea/graphene films in multifunctional sensors and flexible energy storage applications.
  1. Kwon D, et al., IEEE (2017).
  2. Yang ZK, Ma J, Araby S, Shi DJ, Dong WF, Tang T, Chen MQ, J. Power Sources, 412, 655 (2019)
  3. Aakyiir M, et al., J. Appl. Polym. Sci., 138(22), 50509 (2021)
  4. Yaragalla S, Dussoni S, Zahid M, Maggiali M, Metta G, Athanasiou A, Bayer IS, J. Ind. Eng. Chem., 101, 348 (2021)
  5. Nurmakanov Y, Kalimuldina G, Nauryzbayev G, Adair D, Bakenov Z, Nanoscale Res. Lett., 16(1) (2021)
  6. Mittal G, Dhand V, Rhee KY, Park SJ, Lee WR, J. Ind. Eng. Chem., 21, 11 (2015)
  7. Jazzar A, Alamri H, Malajati Y, Mahfouz R, Bouhrara M, Fihri A, J. Ind. Eng. Chem., 99, 1 (2021)
  8. Wu Q, Liu C, Tang L, Yan Y, Qiu H, Pei Y, et al., Soft Matter, 17(1), 68 (2021)
  9. Araby S, Zhang LQ, Kuan HC, Dai JB, Majewski P, Ma J, Polymer, 54(14), 3663 (2013)
  10. Araby S, Su X, Meng Q, Kuan HC, Wang CH, Mouritz A, et al., Nanotechnology, 30(38), 385703 (2019)
  11. Araby S, Saber N, Ma X, Kawashima N, Kang H, Shen H, et al., Mater. Des., 65, 690 (2015)
  12. Fan X, Chen T, Dai L, RSC Adv., 4(70), 36996 (2014)
  13. Ye S, Wang B, Shi Y, Wang B, Zhang Y, Feng Y, et al., Comp. Commun., 21, 100378 (2020)
  14. Liu Y, Huang G, Gao C, Zhang L, Chen M, Xu X, et al., Compos. Sci. Technol., 118, 9 (2015)
  15. Hou Y, Duan L, Gui Z, Hu Y, Compos. Pt. A-Appl. Sci. Manuf., 97, 67 (2017)
  16. Rizvi R, Naguib H, J. Mater. Res., 28(17), 2415 (2013)
  17. Losaria PM, Yim JH, J. Ind. Eng. Chem., 74, 108 (2019)
  18. Khatoon H, Ahmad S, J. Ind. Eng. Chem., 53, 1 (2017)
  19. Yao J, Liu X, Sun H, Liu S, Jiang Y, Yu B, et al., Ind. Eng. Chem. Res., 60(13), 4883 (2021)
  20. Yao HB, Ge J, Wang CF, Wang X, Hu W, Zheng ZJ, Ni Y, Yu SH, Adv. Mater., 25(46), 6692 (2013)
  21. Liu HU, Dong M, Huang W, Gao J, Dai K, Guo J, et al., J. Mater. Chem. C, 5(1), 73 (2017)
  22. Feng C, et al., Compos. B Eng., 194, 108065 (2020)
  23. Wu X, Han Y, Zhang X, Lu C, ACS Appl. Mater. Interfaces, 8(15), 9936 (2016)
  24. Hattori T, Takahashi Y, Iijima M, Fukada E, J. Appl. Phys., 79(3), 1713 (1996)
  25. Johnson JC, Wanasekara ND, Korley LTJ, J Mater Chem B, 2(17), 2554 (2014)
  26. Li T, Zhang C, Xie ZN, Xu J, Guo BH, Polymer, 145, 261 (2018)
  27. Shojaei B, et al., A review on the applications of polyurea in the construction industry. Polymers for Advanced Technologies. n/a(n/a).
  28. Qian X, Song L, Tai Q, Hu Y, Yuen RKK, Compos. Sci. Technol., 74, 228 (2013)
  29. Liu T, Zhao H, Mao F, Li J, Mater. Res. Express, 6(12), 125619 (2019)
  30. Yan J, et al., Int. J. Electrochem. Sci., 15, 10253 (2020)
  31. Huang TC, Yeh LC, Lai GH, Lai FY, Yang TI, Huang YJ, et al., eXPRESS Polym. Lett., 10, 450 (2016)
  32. Zhang C, Li H, Huang A, Zhang Q, Rui K, Lin H, et al., Small, 15(18), 180549 (2019)
  33. Han S, Chand A, Araby S, Cai R, Chen S, Kang H, et al., Nanotechnology, 31(7), 075702 (2020)
  34. Amjadi M, Pichitpajongkit A, Lee S, Ryu S, Park I, ACS Nano, 8(5), 5154 (2014)
  35. Kim JS, Yun JH, Kim I, Shim SE, J. Ind. Eng. Chem., 17(2), 325 (2011)
  36. Li SN, et al., Compos. Sci. Technol., 195, 108173 (2020)
  37. Cui XU, Tian J, Zhang C, Cai R, Ma j, Yang Z, et al., ACS Omega, 6(4), 2526 (2021)
  38. Gong S, et al., Nat Commun, 5, 3132 (2014)
  39. Toader G, Rusen E, Teodorescu M, Diacon A, Stanescu PO, Damian C, et al., J. Appl. Polym. Sci., 134(28), 45061 (2017)
  40. Bakshi SR, Lahiri D, Agarwal A, Int. Mater. Rev., 55, 41 (2010)
  41. Chen H, Muller MB, Gilmore KJ, Wallace GG, Li D, Adv. Mater., 20(18), 3557 (2008)
  42. Cui XU, Tian J, Yu Y, Chand A, Zhang S, Meng Q, Sensors, 20(2), 329 (2020)
  43. Moussa M, El-Kady MF, Wang H, Michimore A, Zhou Q, Xu J, et al., Nanotechnology, 26(7), 075702 (2015)
  44. Li B, et al., Compos. B Eng., 181, 107580 (2020)
  45. Bhunia S, Chatterjee N, Das S, Das Saha K, Bhaumik A, ACS Appl Mater Interfaces, 6(24), 22569 (2014)
  46. Ohsawa Y, Takahashi R, Maruyama S, Matsumoto Y, ACS Macro Lett., 5(9), 1009 (2016)
  47. Lin P, Meng L, Huang Y, Colloids Surf. A: Physicochem. Eng. Asp., 506, 87 (2016)
  48. Shinko A, Jana SC, Meador MA, RSC Adv., 5(127), 105329 (2015)
  49. Zaman I, Kuan HC, Dai J, Kawashima N, Michelmore A, Sovi A, et al., Nanoscale-Cambridge- 4, (15) 4578 (2012).
  50. Zaman I, Kuan HC, Meng QS, Michelmore A, Kawashima N, Pitt T, Zhang LQ, Gouda S, Luong L, Ma J, Adv. Funct. Mater., 22(13), 2735 (2012)
  51. Shi GE, Araby S, Gibson CT, Meng Q, Zhu S, Ma J, Adv. Funct. Mater., 28(19), 170670 (2018)
  52. Han S, et al., Polymer, 184, 121884 (2019)
  53. Araby S, Wang CH, Wu H, Meng Q, Kuan HC, Kim NK, et al., Compos. Pt. A-Appl. Sci. Manuf., 109, 257 (2018)
  54. Parvez K, Li R, Puniredd SR, Hernandez Y, Hinkel F, Wang S, et al., ACS Nano, 7(4), 3598 (2013)
  55. Wan H, Ruan Y, Lv LL, Peng XJ, Miao L, Jiang J, ACS Appl. Mater. Interfaces (2015).
  56. Myers AL, Calles JA, Calleja G, Myers, CaUes and Calleja, 3, (2) 107 (1997).
  57. Lee DW, Choi YS, Microelectron. Eng., 85(5-6), 1054 (2008)
  58. Wu T, Chen B, Sci Rep, 7(1), 17470 (2017)
  59. Sun D, Liu MQ, Guo JH, Zhang JY, Li BB, Li DY, Desalination, 370, 63 (2015)
  60. Han S, et al., Compos. Sci. Technol., 198, 108312 (2020)
  61. Zhou J, et al., Compos. Sci. Technol., 197, 108215 (2020)
  62. Araby S, Li J, Shi GE, Ma Z, Ma J, Compos. Pt. A-Appl. Sci. Manuf., 101, 254 (2017)
  63. Li J, Monaghan T, Nguyen TT, Kay RW, Friel RJ, Harris RA, Compos. B Eng., 113, 342 (2017)
  64. Mohotti D, Ngo T, Raman SN, Ali M, Mendis P, Mater. Des., 56, 696 (2014)
  65. Jiang Y, et al., Int. J. Impact Eng., 133, 103357 (2019)
  66. Kausar A, Am. J. Nanosci. Nanotechnol. Res., 55 (2018).
  67. Aakyiira SA, Michelmorea A, Mengc Q, Amera Y, Yaoa Y, Lid M, Wud X, Zhangd L, Ma J, Nanotechnology (2020).