Polymer(Korea), Vol.45, No.6, 865-871, November, 2021
천연고무와 부타디엔 고무의 혼합-카본블랙 충전제의 분포 정량화
Blends of Natural Rubber and Butadiene Rubber-Distribution Quantification of Carbon Black Filler
E-mail:
The present study deals with the distribution of N330 carbon black in cured 50/50 blend of natural rubber (NR) and butadiene rubber (BR). The results were reported in terms of tan δ and glass transition temperature (Tg). The reduced tan δ peaks in the BR phase with the increased filler loading and the corresponding shift in Tg of BR towards the positive side have shown that there was a preferential migration of carbon black towards the BR phase. Carbon black dispergrader was used to determine the dispersion of the filler on a series of blends with varying BR content. A theoretical evaluation on determining the preference of N330 has also been performed using Wu’s equation. The evaluation was well correlated with the result obtained from analytical data. It has been inferred that the N330 has migrated more towards the BR phase.
- Thielen G, Kautsch. Gummi Kunstst., 61, 377 (2008)
- Hai Le H, Tiwari M, Ilisch S, Radusch HJ, Kautsch. Gummi Kunstst., 58, 575 (2005)
- Fouche PM, McGill WJ, Plast. Rubber Compos. Process. Appl., 18, 317 (1992)
- Supova M, Martynkova GS, Barabaszova KC, Sci. Adv. Mater., 3, 1 (2011)
- Le HH, Ilisch S, Kasaliwal GR, Radusch HJ, Rubber Chem. Technol., 81, 767 (2008)
- Lee HH, Qamer Z, Illisch S, Radusch HJ, Rubber Chem. Technol., 79, 621 (2006)
- Sirisinha C, Prayoonchatphan N, J. Appl. Polym. Sci., 81(13), 3198 (2001)
- Callan JE, Hess WE, Scott CE, Rubber Chem. Technol., 44, 814 (1971)
- Hess WM, Chirico VE, Rubber Chem. Technol., 50, 301 (1977)
- Hess WM, Swor RA, Micek EJ, Rubber Chem. Technol., 57, 959 (1984)
- Walter MH, Keyte DN, Rubber Chem. Technol., 38, 62 (1965)
- Jeon IH, Kim H, Kim SG, Rubber Chem. Technol., 76, 1 (2003)
- Galuska AA, Poulter PR, McElrath KO, Surf. Interface Anal., 25, 418 (1997)
- Portal J, Carrot C, Majeste JC, Cocard S, Pelissier V, Anselme-Bertrand I, Polym. Eng. Sci., 49(8), 1544 (2009)
- Li Y, Wang SF, Zhang Y, Zhang YX, J. Appl. Polym. Sci., 102(1), 104 (2006)
- Mucha M, Marszalek J, Fidrych A, Polymer, 41(11), 4137 (2000)
- Das A, Costa FR, Wagenknecht U, Heinrich G, Eur. Polym. J., 44, 3456 (2008)
- Maiti S, De SK, Bhowmick AK, Rubber Chem. Technol., 65, 293 (1992)
- Kluppel M, Schuster RH, Schapper J, Rubber Chem. Technol., 72, 91 (1999)
- Kluppel M, Schuster RH, Heinrich G, Rubber Chem. Technol., 70, 243 (1997)
- Wang MJ, Morris MD, Kutsovsky Y, Kautsch. Gummi Kunstst., 61, 107 (2008)
- Das D, Satapathy BK, Mater. Chem. Phys., 147(1-2), 127 (2014)
- Schonhorn H, Macromol. Chem. Phys., 93, 262 (1966)
- Mural PS, Madras G, Bose S, RSC Adv., 4, 4943 (2014)
- Sumita M, Sakata K, Asai S, Miyasaka K, Nakagawa H, Polym. Bull., 25, 265 (1991)
- Stickney PS, Mueller WJ, Rubber Chem. Technol., 42, 604 (1969)
- Lee BL, Polym. Eng. Sci., 25, 729 (1985)
- Gubbels F, Blacher S, Vanlathem E, Jerome R, Deltour R, Brouers F, Teyssie P, Macromolecules, 28(5), 1559 (1995)
- Raiati M, Kalaee M, Mazinani S, Rubber Chem. Technol., 90, 751 (2017)
- Wang K, Liang S, Deng JN, Yang H, Zhang Q, Fu Q, Dong X, Wang DJ, Han CC, Polymer, 47(20), 7131 (2006)
- Warasitthinon N, Robertson CG, Rubber Chem. Technol., 91, 577 (2018)
- Bandyopadhyay A, Thakur V, Pradhan S, Bhowmick AK, J. Appl. Polym. Sci., 115(2), 1237 (2010)
- Bose S, Bhattacharyya AR, Kulkarni AR, Potschke P, Compos. Sci. Technol., 69, 365 (2009)
- Hiep NQ, Huy TH, Nguyen PC, Sy DT, Khang DQ, Vietnam J. Chem., 57, 213 (2019)
- Otto S, Randl O, Goncalveset O, Cantaloube B, Kautsch. Gummi Kunstst., 58, 390 (2005)
- Dong AN, Zhiyi Z, Haixiang J, Jinquan S, Huan Z, Yaqing L, Rubber Chem. Technol., 90, 611 (2017)
- Narongthong J, Sae-Oui P, Sirisinha C, Rubber Chem. Technol., 91, 521 (2018)
- Rooj S, Das A, Stockelhuber KW, Wang DY, Galiatsatos V, Heinrich G, Soft Matter, 9, 3798 (2013)
- Das D, Satapathy BK, Mater. Chem. Phys., 147(1-2), 127 (2014)