화학공학소재연구정보센터
Korean Journal of Materials Research, Vol.31, No.11, 593-600, November, 2021
Facile Synthesis of g-C3N4 Modified Bi2MoO6 Nanocomposite with Improved Photoelectronic Behaviors
E-mail:,
Herein, a series of g-C3N4 modified Bi2MoO6 nanocomposites using Bi2MoO6 and melamine as original materials are fabricated via sintering process. For presynthesis of Bi2MoO6 an ultrasonic-assisted hydrothermal technique is researched. The structure and composition of the nanocomposites are characterized by Raman spectroscopy, X-ray diffraction (XRD), and high-resolution field emission scanning electron microscopy (SEM). The improved photoelectrochemical properties are studied by photocurrent density, EIS, and amperometric i-t curve analysis. It is found that the structure of Bi2MoO6 nanoparticles remains intact, with good dispersion status. The as-prepared g-C3N4/Bi2MoO6 nanocomposites (BMC 5-9) are selected and investigated by SEM analysis, which inhibits special morphology consisting of Bi2MoO6 nanoparticles and some g-C3N4 nanosheets. The introduction of small sized g-C3N4 nanosheets in sample BMC 9 is effective to improve the charge separation and transfer efficiency, resulting in enhancing of the photoelectric behavior of Bi2MoO6. The improved photoelectronic behavior of g-C3N4/Bi2MoO6 may be attributed to enhanced charge separation efficiency, photocurrent stability, and fast electron transport pathways for some energy applications.
  1. Wang F, Banerjee D, Liu YS, Chen XY, Liu XG, Analyst, 135, 1839 (2010)
  2. Zhang BB, Wang L, Zhang YJ, Ding Y, Bi YP, Angew. Chem.-Int. Edit., 57, 2248 (2018)
  3. Burda C, Chen XB, Narayanan R, El-Sayed MA, Chem. Rev., 105(4), 1025 (2005)
  4. Besteman K, Lee JO, Wiertz F, Heering HA, Dekker C, Nano Lett., 3, 727 (2003)
  5. Cong FZ, Hong W, Tian XR, Xu HX, Front. Phys., 7, 521 (2012)
  6. Osterloh FE, Chem. Soc. Rev., 42, 2294 (2013)
  7. Yao T, An X, Han H, Chen JQ, Li C, Adv. Energy Mater., 8, 180021 (2018)
  8. Zhao S, Dai Z, Guo WJ, Chen FX, Liu YL, Chen R, Appl. Catal. B: Environ., 244, 206 (2019)
  9. Tian GH, Chen YJ, Zhai RT, Zhou J, Zhou W, Wang RH, Pan K, Tian CG, Fu HG, J. Mater. Chem. A, 1, 6961 (2013)
  10. Tian J, Hao P, Wei N, Cui HZ, Liu H, ACS Catal., 5, 4530 (2015)
  11. Zhong DK, Choi S, Gamelin DR, J. Am. Chem. Soc., 133(45), 18370 (2011)
  12. Rettie JE, Lee HC, Marshall LG, et al., J. Am. Chem. Soc., 135, 11389 (2013)
  13. Zhou F, Shi R, Zhu YF, J. Mol. Catal. A-Chem., 340(1-2), 77 (2011)
  14. Zhang MY, Shao CL, Mu JB, Huang XM, Zhang ZY, Guo ZC, Zhang P, Liu YC, J. Mater. Chem., 22, 577 (2012)
  15. Lai KR, Wei W, Zhu YT, Guo M, Dai Y, Huang BB, J. Solid State Chem., 187, 103 (2012)
  16. Wang Y, Wang X, Antonietti M, Angew. Chem.-Int. Edit., 51, 68 (2012)
  17. Dong G, Zhang Y, Pan Q, Qiu J, J. Photochem. Photobiol. C, 20, 33 (2014)
  18. Li XH, Antonietti M, Chem. Soc. Rev., 42, 6593 (2013)
  19. Li HP, Liu JY, Hou WG, Du N, Zhang RJ, Tao XT, Appl. Catal. B: Environ., 160, 89 (2014)
  20. Zhen YZ, Yang CM, Fu F, Shen HD, Xue WW, Gu CR, Feng JH, zhang YC, Liang YC, Phys. Chem. Chem. Phys., 22, 26278 (2020)
  21. Ma Y, Wang ZH, Jia YL, Wang LN, Yang M, Qi YX, Bi YP, Carbon, 114, 591 (2017)
  22. Wang PF, Ao YH, Wang C, Hou J, Qian J, Carbon, 50, 5256 (2012)
  23. Zhang G, Zhang J, Zhang M, Wang X, J. Mater. Chem., 22, 8083 (2012)
  24. Yan T, Yan Q, Wang XD, Liu HY, Li MM, Lu SX, Xu WG, Sun M, Dalton Trans., 44, 1601 (2015)
  25. Li Y, Wang J, Tian X, Ma L, Dai C, Yang C, Zhou Z, Nanoscale, 8, 1676 (2016)
  26. Ali HE, Khairy Y, Optik, 178, 90 (2019)
  27. Zhang XY, Li MY, He LM, Tian DD, Zhang LJ, Zhang JH, Liu M, J. Alloy. Compd., 864, 157905 (2021)
  28. Zhao J, Yan JH, Jia HJ, Zhong SW, Zhang XY, Xu L, J. Mol. Catal. A-Chem., 424, 162 (2016)
  29. Fu K, Pan YH, Ding C, Shi J, Deng HP, J. Photochem. Photobiol. A-Chem., 412, 113235 (2021)
  30. Fu M, Pi JM, Dong F, Duan QY, Guo H, Int. J. Photoenergy, 2013, 158496 (2013)
  31. Zhang LW, Xu TG, Zhao X, Zhu YF, Appl. Catal. B: Environ., 98(3-4), 138 (2010)
  32. MacZka M, Freire PTC, Luz-Lima C, Paraguassu W, Hanuza J, Filho JM, J. Phys.: Condens. Matter, 22, 015901 (2010)
  33. Li HH, Liu CY, Li KW, Wang H, J. Mater. Sci., 43(22), 7026 (2008)