화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.39, No.1, 216-226, January, 2022
DOI10.1007/s11814-021-0892-3  Export Citation
Kinetics, isothermal and mechanistic insight into the adsorption of eosin yellow and malachite green from water via tri-metallic layered double hydroxide nanosheets
Muhammad Altaf Nazir1, Tayyaba Najam2, Muhammad Sohail Bashir3, Muhammad Sufyan Javed4, Muhammad Aswad Bashir1, Muhammad Imran5, Umair Azhar6, †, Syed Shoaib Ahmad Shah1, 3, †, and Aziz ur Rehman1, †
  • 1Institute of Chemistry, The Islamia University of Bahawalpur, Bahawalpur 63100, I. R. Pakistan
  • 2Institute for Advanced Study, Shenzhen University, Shenzhen 518060, P. R. China
  • 3Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Soft Matter Chemistry, School of Chemistry and Materials Science, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China
  • 4School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, P. R. China
  • 5Department of Chemistry, Faculty of Science, King Khalid University, P.O. Box 9004, Abha 61413, Saudi Arabia
  • 6Department of Polymer Engineering, National Textile University Karachi Campus, Karachi 74900, I. R. Pakistan
E-mail:, ,
The use of highly efficient, environment-friendly and economically inexpensive materials for the adsorption removal of contaminants from water has always been considered as emerging task. In this study, we synthesized hybrid tri-metallic nickel cobalt layered double hydroxide (NiCoAl-LDH) porous material for the adsorption removal of Eosin yellow (EY) and Malachite green (MG) from water. The characterization results disclosed that tri-metallic LDH has been synthesized with extraordinary purity, identical morphology and high surface area (134.21 m2ㆍg-1). The NiCoAl-LDH performs the best for adsorption of EY (qe=37.30mgㆍg-1 at pH=2) and MG (qe=39.61 mgㆍg-1 at pH= 10). The Langmuir and Freundlich isotherm models were applied to explain the adsorption process of dyes on the surface of LDH. The Langmuir model (R2=0.991 and 0.999 for Eosin Y and Malachite G, respectively) was very appropriate to explain the process of adsorption on NiCoAl-LDH as homogeneous (monolayer). The maximum adsorption capacity of EY and MG calculated with Langmuir model was 78.74 and 110.13mgㆍg-1 at 30 °C, respectively. Also with 240 minutes contact time 94.8% EY and 89.9% MG was adsorbed by as synthesized NiCoAl-LDH nanosheets. The NiCoAl-LDH nanosheets showed excellent performance of reusability of up to five regeneration cycles. The results showed that the adsorption capacity of NiCoAl-LDH nanosheets after five regeneration cycles, to adsorb EY, decreased only from 40.80 to 36.93mgㆍg-1 and that of MG from 79.21 to 75.42mgㆍg-1, which is acceptable. The overall results Suggest that the fabricated NiCoAl-LDH is favorable for the purification of dye contaminated water.
Keywords:LDH;Layered Double Hydroxide;NiCoAl-LDH;Eosin Yellow;Malachite Green;Dye Adsorption;Purification of Water
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