ZIF-67을 이용한 이기능성 촉매의 최신연구 동향

김상준; 조승근; 박길령; 이은빈; 이재민; 이정우; Sang Jun Kim; Seung Geun Jo; Gil-Ryeong Park; Eun Been Lee; Jae Min Lee; Jung Woo Lee

Korean Journal of Materials Research, Vol.32, No.2, 98-106, February, 2022

DOI10.3740/MRSK.2022.32.2.98 Export Citation

ZIF-67을 이용한 이기능성 촉매의 최신연구 동향

Recent Research Trend of Zeolitic Imidazolate Framework-67 for Bifunctional Catalyst

김상준^{1, 2}, 조승근¹, 박길령¹, 이은빈¹, 이재민¹, 이정우^{1, †}

¹부산대학교 재료공학과
²부산대학교 소재기술연구소

Sang Jun Kim^{1, 2}, Seung Geun Jo^{1, 3}, Gil-Ryeong Park^{1, 3}, Eun Been Lee^{1, 3}, Jae Min Lee^{1, 3}, and Jung Woo Lee^{1, 3, †}

¹Department of Materials Science and Engineering,, Pusan National University, Busan 46241, Republic of Korea
²Institute of Materials Technology, Pusan National University, Busan 46241, Republic of Korea
³, Korea

E-mail:

Metal-organic frameworks (MOFs) are widely used in various fields because they make it easy to control porous structures according to combinations of metal ions and organic linkers. In addition, ZIF (zeolitic imidazolate framework), a type of MOF, is made up of transition metal ions such as Co2+ or Zn2+ and linkers such as imidazole or imidazole derivatives. ZIF-67, composed of Co2+ and 2-methyl imidazole, exhibits both chemical stability and catalytic activity. Recently, due to increasing need for energy technology and carbon-neutral policies, catalysis applications have attracted tremendous research attention. Moreover, demand is increasing for material development in the electrocatalytic water splitting and metal-air battery fields; there is also a need for bifunctional catalysts capable of both oxidation/reduction reactions. This review summarizes recent progress of bifunctional catalysts for electrocatalytic water splitting and metal-air batteries using ZIF-67. In particular, the field is classified into areas of thermal decomposition, introduction of heterogeneous elements, and complex formation with carbonbased materials or polyacrylonitrile. This review also focuses on synthetic methods and performance evaluation.

Keywords:metal-organic framework;ZIF-67, water splitting;metal-air battery;bifunctional catalyst

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