PILs modified PMoW on silicon with hierarchical functional structure for ultra-deep oxidative desulfurization

Jiarong Li; Chang Li; Lilong Yang; Zhe Liu; Ruimin Gao; Jianshe Zhao

Journal of Industrial and Engineering Chemistry, Vol.109, 338-346, May, 2022

DOI10.1016/j.jiec.2022.02.022 Export Citation

PILs modified PMoW on silicon with hierarchical functional structure for ultra-deep oxidative desulfurization

Jiarong Li, Chang Li, Lilong Yang¹, Zhe Liu, Ruimin Gao², and Jianshe Zhao^†

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Northwest University, Xi’an, Shaanxi 710127, China
¹Petroleum Systems Engineering, Faculty of Engineering and Applied Science, University of Regina, Regina S4S OA2, Canada
²Shaanxi Yanchang Petroleum Group Corp. Ltd., Xi’an 710075, China

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In order to obtain the clean fuel, two types of inorganic–organic hybrid catalysts with core–shell structures have been prepared as efficient and reusable catalysts for oxidative desulfurization, in which ionic liquids (1-vinylimidazole and 4-vinylpyridine) were grafted and polymerized on the surface of silicon through free radical polymerization and polyoxometalates (H3PMo6W6O40, attributed as PMoW) was functionalized on the surface of silicon. The as-prepared catalysts were characterized by FT-IR, UV–Vis, N2 adsorption–desorption, SEM and TEM. It could be proved that these two types of catalysts show high sulfur removal efficiency over 98% in the model fuel with 2000 ppm of DBT under mild reaction condition. The effective catalytic abilities of synthesized catalysts are mainly attributed to the hierarchical functional core–shell structures. The successful preparation of the PILs-polyoxometalates based catalysts with high catalytic activities could provide the demonstration of the application of polymer in oxidative desulfurization.

Keywords:Oxidation catalysis;Desulfurization;Poly(ionic liquid)s;Polyoxometalates;Core-shell catalysts

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[2] Piscopo CG, Granadeiro CM, Balula SS, Boškovic D, ChemCatChem, 12(19), 4721 (2020)

[3] Wang H, Tang M, Shi F, Ding R, Wang L, Wu J, Li X, Liu Z, Lv B, ACS Appl. Mater. Interfaces (2020)

[4] Li W, Zhou C, Fuel, 227, 141 (2018)

[5] Wang X, Xiao C, Mei J, Alabsi MH, Shi Y, Zhao Z, Duan A, Huang KW, Xu C, ACS Appl. Mater. Interfaces, 12(36), 40404 (2020)

[6] Rezvani MA, Shaterian M, Akbarzadeh F, Khandan S, Chem. Eng. J., 333, 537 (2018)

[7] Rezvani MA, Hadi M, Mirsadri SA, Appl. Organomet. Chem. (2020)

[8] Bryzhin AA, Gantman MG, Buryak AK, Tarkhanova IG, Appl. Catal. B: Environ., 257, 117938 (2019)

[9] Li SW, Yang Z, Gao RM, Zhang G, Zhao JS, Appl. Catal. B: Environ., 221, 574 (2018)

[10] Zhu J, Wu P, Chen L, He J, Wu Y, Wang C, Chao Y, Lu L, He M, Zhu W, Li H, Chemistry, 45, 91 (2020)

[11] Gao H, Wu X, Sun D, Niu G, Guan J, Meng X, Liu C, Xia W, Song X, J. Chem. Soc.-Dalton Trans., 48, 5749 (2019)

[12] Zhao X, Zhu G, Jiao L, Yu F, Xie C, Chemistry, 24, 11021 (2018)

[13] Wang S, Zhang X, Chang X, Zong MY, Fan CZ, Guo DX, Xu J, Wang DH, Bu XH, Appl. Catal. B: Environ., 298, 120594 (2021)

[14] Jiang W, Zhu K, Li H, Zhu L, Hua M, Xiao J, Wang C, Yang Z, Chen G, Zhu W, Li H, Dai S, Chem. Eng. J., 394, 124831 (2020)

[15] Ma Y, Li A, Wang C, Ge X, Chem. Eng. J., 404, 127062 (2021)

[16] Taghiyar H, Yadollahi B, Sci. Total Environ., 708, 134860 (2020)

[17] Jiang W, Jia H, Fan X, Dong L, Guo T, Zhu L, Zhu W, Li H, Appl. Surf. Sci., 484, 1027 (2019)

[18] Mirzaei M, Eshtiagh-Hosseini H, Alipour M, Frontera A, Coord. Chem. Rev., 275, 1 (2014)

[19] Wang C, Liu Z, Gao R, Liu J, An S, Zhang R, Zhao J, New J. Chem., 44(16), 6251 (2020)

[20] Zhang X, Zhu Y, Huang P, Zhu M, RSC Adv., 6(73), 69357 (2016)

[21] Gao Y, Lv Z, Gao R, Zhang G, Zheng Y, Zhao J, J. Hazard. Mater., 359, 258 (2018)

[22] Samaniyan M, Mirzaei M, Khajavian R, Eshtiagh-Hosseini H, Streb C, ACS Catal., 9(11), 10174 (2019)

[23] Chang X, Yang XF, Qiao Y, Wang S, Zhang MH, Xu J, Wang DH, Bu XH, Small, 16, 1906432 (2020)

[24] Liao X, Huang Y, Zhou Y, Liu H, Cai Y, Lu S, Yao Y, Appl. Surf. Sci., 484, 917 (2019)

[25] Rizzo C, Misia G, Marullo S, Billeci F, D’Anna F, Green Chem., 24, 1318 (2022)

[26] Liu L, Guo F, Xu J, Hu J, Wang H, Liu H, Wang M, Fuel, 244, 439 (2019)

[27] Yang H, Jiang B, Sun Y, Zhang L, Huang Z, Sun Z, Yang N, J. Hazard. Mater., 333, 63 (2017)

[28] Li SW, Gao RM, Zhang RL, Zhao JS, Fuel, 184, 18 (2016)

[29] Li J, Yang Z, Hu G, Zhao J, Chem. Eng. J., 388, 124325 (2020)

[30] Ma Z, Zhang J, Zhan H, Xu M, Yang H, Yang L, Bai L, Chen H, Wei D, Wang W, Process Saf. Environ. Protect., 140, 26 (2020)

[31] Eseva E, Akopyan A, Schepina A, Anisimov A, Maximov A, Catal. Commun., 149, 106256 (2021)

[32] Wu P, Sun Y, Chen L, Jia Q, He J, Ma W, Lu L, Chao Y, Fan L, Zhu W, Inorg. Chem., 61, 633 (2022)

[33] Ahmed I, Puthiaraj P, Chung YM, Ahn WS, Fuel Process. Technol., 215, 106741 (2021)

[34] Rajendran A, Fan HX, Cui TY, Feng J, Li WY, J. Clean Prod., 334, 130199 (2022)

[35] Kargar H, Ghahramaninezhad M, Shahrak MN, Balula SS, Microporous Mesoporous Mater., 317, 110992 (2021)

[36] Gu Y, Luo H, Xu W, Zhou W, Sun Y, J. Ind. Eng. Chem., 105, 435 (2022)

[37] Zhang T, Chen X, Ding B, Ding Z, Wang Y, Qiu H, Jiang Y, Dai S, Hou Z, Energy Fuels, 36, 1402 (2022)

[38] Ye G, Hu L, Gu Y, Lancelot C, Rives A, Lamonier C, Nuns N, Marinova M, Xu W, Sun Y, J. Mater. Chem. A, 8, 19396 (2020)