The purpose of this study is development of separation processes by which metal elements worth using for raw materials of chemicals (for examples Cd, Cu, Mn, Ph, Zn and so on) are recovered from incineration fly ash of municipal solid wastes. Candidate Process (D) evolved out of Candidate Process (C), which was synthesized with a computer-aided procedure. The process consists of addition of Na2S to nitric solution as leachate of the fly ash for forming precipitate of sulfides, and consecutive dissolution of sulfides with dil-H2SO4, conc-H2SO4 and HNO3 to separate Mn2+, Zn2+ and Cd2+ from each other and to leave CuS insoluble in the acids. For further purification of metals, Candidate Process (D) was modified into Candidate Process (E), in which solvent extraction of Zn2+ from Mn2+ and Cd2+ fractions with bis (2-ethylhexyl) phosphoric acid (D 2 EHPA), and addition of NH(3)aq or (NH4) 2CO3 to form [Cu(NH3)(4)](2+) and to leave PbS insoluble were adopted.