화학공학소재연구정보센터
Langmuir, Vol.12, No.20, 4718-4722, 1996
Viscosity of Wormlike Micelles - Determination of the End Cap Energy and Persistence Length
We propose a theory for the zero-shear viscosity of a dilute solution of wormlike micelles, with a length distribution as derived by Israelachvili, Mitchell, and Ninham. An analytical approach using Bohdanecky’s approximation to the full Yamakawa-Fujii-Yoshizaki description (YFY) for the viscosity of wormlike objects is combined with a numerical integration of the YFY equations. In principle, this provides a convenient means of extracting the growth parameters, dimensions, and persistence length of linear micelles from measurements of the viscosity as a function of the surfactant concentration.