Langmuir, Vol.13, No.9, 2494-2497, 1997
Phase Inversion Temperatures of Macroemulsions and Microemulsions
There exists a parallelism between emulsions and the corresponding microemulsions. In this framework and on the basis of the Gibbs adsorption equation, an explanation is provided for the experimental observation that the phase inversion temperature of a macroemulsion almost coincides with the phase inversion temperature of the corresponding middle phase microemulsion in equilibrium with the two excess phases.