Langmuir, Vol.13, No.25, 6726-6730, 1997
Some Aspects of Fluid Behavior in Unwetted Micropores from Computer-Simulations
The behavior of a Stockmayer fluid in unwetted slit and cylindrical capillaries is discussed and compared to that of a Lennard-Jones fluid. For a Lennard-Jones fluid in a slit capillary, a convex meniscus is observed in the direct computer simulations. The influence of the isothermal compressibility on the density in micropores is studied.
Keywords:LIQUID-VAPOR COEXISTENCE;CANONICAL MONTE-CARLO;SLIT-LIKE PORES;ADSORPTION HYSTERESIS;CYLINDRICAL PORE