화학공학소재연구정보센터
Macromolecules, Vol.27, No.2, 337-347, 1994
Rheological Characterization of Director Dynamics in a Nematic Monodomain Containing Mesogenic Polymers of Differing Architectures
The theological behavior of dilute nematic mixtures containing liquid crystal polymers (LCP) with different molecular architectures dissolved in low molar mass nematogens is investigated. Addition of a side-chain LCP (MSHMA) to a flow-aligning nematic solvent, pentylcyanobiphenyl (5CB), alters the theology to director-tumbling character. Conversely, dissolution of a main-chain LCP (TPB-15) in a director-tumbling nematic, octylcyanobiphenyl (8CB), suppresses the tumbling behavior and produces a flow-aligning response. A characteristic pattern of shear stress oscillations is observed for MSHMA/5CB mixtures and pure 8CB, indicative of director tumbling, in flow startup, step flow, and flow reversal experiments. In contrast, TPB-15/8CB and TPB-15/5CB mixtures show no oscillatory response but a single stress overshoot, characteristic of a flow-aligning nematic such as pure 5CB. Concentration and temperature dependences of the theological effect of LCP are presented. Our results demonstrate that addition of sufficient amounts of LCP to a nematic solvent can change the sign of the Leslie viscosity coefficient alpha(3). Our findings are qualitatively consistent with a theoretical model of Brochard (1979), provided that the side-chain LCP has an oblate molecular configuration, while the main-chain LCP maintains a prolate molecular configuration in the nematic solvent. Analysis of the transient shear response function via the Erickson-Leslie-Parodi formalism yields viscosity coefficients of the mixtures and hence an estimate of the effective axial ratio of the polymer chain.