Macromolecules, Vol.28, No.21, 7085-7087, 1995
Melt Viscosity of Main-Chain Thermotropic Liquid-Crystalline Polymers Without Flexible Spacers
Viscoelastic properties for a series of all-aromatic main-chain thermotropic copolymers based on random units of 75% 1-hydroxy-4-benzoic acid and 25% 2-hydroxy-6-naphthoic acid (B-N, 3:1) were measured in the nematic state. Zero-shear rate viscosity eta(0) obtained from small-strain oscillatory and steady-state measurements reveals that eta(0) scales with the molecular weight with a power of 4.1, i.e., eta(0) proportional to M(4.1). Measurements of viscosity for the small-molecule liquid crystal (SMLC) bis[4-(phenoxycarbonyl)-phenyl] 1,4-benzenedicarboxylic acid ester and data for other SMLC compounds taken from the literature establish that this power dependence holds over a range covering 3 decades in molecular weight and 8 decades in viscosity. This exponent 4.1 is distinctly different from that of conventional polymer melts, 3.4, but lies within the range of values reported for nematic polymers with flexible spacers.
Keywords:ROD-LIKE MACROMOLECULES;CONCENTRATED-SOLUTION;RHEOLOGICAL BEHAVIOR;SHEAR BEHAVIOR;NEMATIC STATE;DYNAMICS