화학공학소재연구정보센터
Macromolecules, Vol.31, No.26, 9258-9264, 1998
Shear-induced order in aqueous micellar solutions of amphiphilic poly(tert-butylstyrene)-b-poly(Na methacrylate) diblock
Shear-induced order of aqueous micellar solutions of a poly(tert-butylstyrene)-b-poly(sodium methacrylate) diblock (c = 2.5-15 w/v %) has been investigated by small-angle X-ray scattering. Data collected from a Couette cell in both radial and tangential geometries agree with a crystalline ordering of micelles in close packed hexagonal lavers perpendicular to the velocity gradient, when c is in the 5-10 w/v % range. The measured interlayer distance is indeed very close to the value expected for a close-packed structure. The experimental data are consistent with a zigzag motion of adjacent planes upon shear. Shear-induced order is, however, restricted to a narrow concentration range just above the concentration for the sol-gel transition. This domain is thought to correspond to a regime where relative layer translation modes are allowed whereas mutual rotation is hindered.