Materials Research Bulletin, Vol.29, No.12, 1239-1246, 1994
An Investigation of Electrochemically and Chemically Polymerized Indole
Doped polyindole can be obtained either after anodic oxidation of indole, C8NH7, in various electrolytic solutions or after indole chemical oxidation in acetonitrile - oxidizing agent (FeCl3, CuCl2, KIO3) solutions. This conducting polymer exhibits a good air stability with room temperature electrical conductivities, in the range 10(-3) to 10(-1) S.cm-1, depending on the nature of the counterion and on the polymerization process. The influence of the experimental synthesis conditions on the morphology of the chemically obtained polyindole is examined.