Applied Catalysis A: General, Vol.225, No.1-2, 43-49, 2002
Catalytic methoxycarbonylation of 1,6-hexanediamine with dimethyl carbonate to dimethylhexane-1,6-dicarbamate using Bi(NO3)(3)
The Bi(NO3)(3), prepared by evacuating Bi(NO3)(2).5H(2)O at 353 K for 3 h, showed a high catalytic activity for the methoxycarbonylation of 1,6-hexanediamine with dimethyl carbonate to form dimethylhexane-1,6-dicarbamate, the yield of which reached 84% at 353 K in 18 h.