Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol.281, 79-90, 1996
Additive Partial Chiral Properties of a Thermotropic Liquid-Crystal with 2 Chiral Centers
Temperature dependent measurements of the pitch of the cholesteric phase and the spontaneous polarization of the smectic C* phase are presented for five configurations of a thermotropic liquid crystal with two chiral centers. The temperature dependent chiral properties of the two diastereoisomers (S,S)-M96 and (S,R)-M96 are additively composed by the partial contributions of the individual chiral centers, determined from the partially racemic configurations. Mixtures of the diastereoisomers exhibit a mole fraction weighted additivity of the chiral properties.