Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol.285, 163-168, 1996
Anomalous C-13/N-15 Isotope Effect in the Pi-D System (DME-DCNQI)(2)Cu Studied by Selective Isotope Substitution
D, C-13 and N-15 isotopes were selectively introduced to the p pi-d system (DMe-DCNQI)(2)Cu. Anomalously remarkable isotope effect was found in C-13 or N-15 substitutions of the terminal cyanoimino groups as well as deuteration of the methyl groups.
Keywords:CONDUCTOR (2;5 DM-DCNQI)2CU;MOLECULAR CONDUCTOR;PHASE-TRANSITION;RADICAL SALTS;ORGANIC METAL;DME-DCNQI=2;5-DIMETHYL-N;N’-DICYANOQUINONEDIIMINE;CRYSTAL;R1