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Applied Catalysis B: Environmental, Vol.5, No.1-2, 165-179, 1994
Effects of Rhodium Addition on Methane Oxidation Behavior of Alumina-Supported Noble-Metal Catalysts
Laboratory methane oxidation experiments were conducted using a series of catalyst samples prepared by impregnating Ph-free noble metal catalysts (i.e., Pt/Pd, Pt or Pd) with various amounts of rhodium (0.0035, 0.005, and 0.014 wt.-% Rh). The addition of these small amounts of rhodium did not significantly change the temperature required for the onset of the methane oxidation. However, variable-composition experiments conducted at a temperature characteristic of warmed-up catalytic converters (ca. 550 degrees C) reveal that the rhodium addition tends to shift the optimum feedstream stoichiometry (at which a maximum methane conversion occurs) toward more reducing conditions. These Rh-induced effects on methane conversion behavior appear to be independent of how the rhodium is incorporated in the catalyst.
Keywords:PALLADIUM