Petroleum Chemistry, Vol.37, No.5, 408-413, 1997
Mechanism of hydrogenation of aromatic nitro compounds on palladium-containing polymers
On the basis of a study of the kinetics of the liquid-phase hydrogenation of aromatic nitro compounds on palladium-containing polymers, a possible mechanism of the process is proposed and discussed, Initially the nitro compound molecules react with catalyst metal centres containing activated hydrogen, The adduct formed "collects" deficient activated hydrogen from the "surface" of the catalyst, after which the amine produced is forced out into solution by molecular hydrogen,