화학공학소재연구정보센터
Polymer, Vol.35, No.24, 5279-5282, 1994
Rejuvenation of Epoxy Glasses Subjected to Uniaxial Compression
Two epoxy networks, differing significantly in their glass transition temperatures (T(g)s), were subjected to uniaxial compression tests in the glassy state (20 degrees C). One of the systems was based on the diglycidyl ether of bisphenol-A (DGEBA) cured with ethylenediamine (EDA). The other one was based on an epoxidized novolac (EPN) cured with 4,4’-diaminodiphenyl sulfone (DDS). Both systems were physically aged by specific thermal treatments. The endothermic enthalpy relaxation peak, characteristic of aged glasses, could be erased at temperatures well below T-g by large mechanical deformations, i.e. close to the incipient strain hardening level in uniaxial compression tests. This phenomenon, which was accompanied by an increase in specific volume, constitutes a clear manifestation of rejuvenation produced by large mechanical stimuli. The validity of statements presenting an opposite point of view is also discussed.