4-(N, N-Diallylamino)pyridine (DAAP) and N, N-diallylaminobenzene (DAAB), each having only a single diallylamino group, and N,N,N’,N’-tetrallyl-4,4’-diaminobenzidine (AAB), N,N,N’,N’-diaminodiphenylsuflone (AABS) and N,N,N’,N’-tetrallyl-4,4’-diaminodiphenyl ether (AABE), each of which has two diallylamino groups, were prepared by means of N-alkylation reaction involving aromatic amines and allyl chloride in the presence of a phase-transfer catalyst. Linear poly(DAAP), poly(DAAP-co-DAAB) and network poly(DAAP-co-AAB), poly(DAAP-co-AABS) and poly(DAAP-co-AABE), all being polymers containing supernucleophilic groups, were synthesized by cyclopolymerization and copolymerization.