Polymer, Vol.37, No.16, 3537-3541, 1996
Loop-Like Light Extinction in the Precipitation Film of a Presheared Lyotropic Polymeric Liquid-Crystal
This paper reports a novel light extinction pattern of polymers in a polarizing microscope, termed as looplike extinction by the authors. Such a phenomenon is found together with the Maltese cross, in the precipitation film of presheared poly(1,4-phenylene terephthalamide) (PPTA) solution, a popular lyotrophic polymeric liquid crystal. A plausible supermolecular structure is assumed, which comprises one +1 defect and a pair of -1/2 defects. The key structure is that besides the core of the nematic droplet, the matrix is also anisotropic due to preshearing. Calculated birefringence patterns find good agreement with the experimental micrographs.
Keywords:ORIENTED THERMOTROPIC POLYMERS;NEMATIC DROPLETS;OPTICAL MICROSCOPY;BANDED STRUCTURES;TEXTURES;FIELD;DISCLINATIONS;MORPHOLOGY;SCATTERING;CELLULOSE