Polymer, Vol.37, No.25, 5735-5738, 1996
On the Morphology and Crystallization Kinetics of Monodisperse Polyethylene Oligomers Crystallized from the Melt
The melt crystallization of three monodisperse paraffins, C294H590, C246H494 and C198H398, has been studied optically as a function of temperature. In both C294H590 and C246H494, a distinct minimum in the rate of crystal growth has been observed, corresponding to a transition from predominantly chain-extended crystallization at high temperatures to the growth of crystals in which the molecules adopt a once-folded conformation. This change in molecular conformation is accompanied by a change in optical texture. Well below the minimum, morphologies, are spherulitic and closely resemble polyethylene. When crystals contain chain-extended molecules, highly birefringent, coarse lamellar textures develop. In C198H398, no minimum in the crystal growth rate has been observed; this system does, however, exhibit similar morphological trends to those seen in C294H590 and C246H494.