화학공학소재연구정보센터
Polymer, Vol.39, No.26, 7113-7117, 1998
Effect of silane coupling agent on the chemorheological behaviour of epoxidised natural rubber filled with precipitated silica
Results of measurements of physical properties and solvent swelling of the extrudates indicate that epoxidised natural rubber (ENR) interacts chemically with precipitated silica when the mix of the two was extruded at 150-170 degrees C in a Monsanto Processability Tester (MPT). The extent of interaction between the rubber and the filler depends on the extrusion time, the volume fraction of the filler, the shear rate and the addition of the silane coupling agent, namely N-3-(N-vinyl benzyl amino) ethyl-gamma-amino propyl trimethoxy silane monohydrochloride. The activation energy of the chemical interaction between ENR and silica decreases on the addition of the silane coupling agent.