Polymerizable enamines were synthesized by the reaction of 2-acetoacetoxyethyl methacrylate (AAEMA) with various aliphatic mono- and diamines. The enamines were characterized by elemental analyses, IR, H-1 NMR and C-13 NMR spectroscopy. Radical polymerization of synthesized enamines yielded polymers with pendant enamine groups which were also prepared by the reaction of poly(AAEMA) with the corresponding amines.