We investigated the effect of poly(ethylene-co-vinyl alcohol) (EVOH) concentration on the processability and physical properties of thermoplastic starch plasticized with glycerine and water. Waxy maize starch (Amioca), native com starch (Melogel), and a treated high amylose com starch (Hylon VII) were employed to explore the effect of starch type on blend properties. All the starches exhibited similar changes in properties with increasing EVOH content. The minimum injection pressure required for filling a standard test specimen (a measure of processability) decreased with increasing EVOH concentration and provided an indication of improved processability. Blends with high amylose com exhibited higher injection pressures than the corresponding waxy maize or native com starch blends. The ductility of all the thermoplastic starches was significantly increased upon the addition of EVOH. The waxy maize blends were stiffer and the high amylose com blends exhibited higher elongation at low EVOH concentrations, but all the starch/EVOH blends exhibited similar physical properties when the EVOH concentration was greater-than-or-equal-to 50 wt%. An investigation of physical properties of this blend series after long term aging from 10% to 90% relative humidity is in progress. Future studies include rheology, electron microscopy, and thermal analysis to more fully elucidate phase behavior in these binary blends.