화학공학소재연구정보센터
Polymer Engineering and Science, Vol.36, No.4, 483-494, 1996
Structure and Properties of Biaxially Stretched Poly(Ethylene-Terephthalate) Sheets
Huge numbers of PET (poly[ethylene terephthalate]) bottles are produced in the world. Especially in Japan, the number of hot-fillable PET bottles used is extremely large and is still increasing. This type of bottle is generally manufactured by the heat-set method using hot molds after stretch-blow molding. Herein, we examined how the PET sheet stretching condition affects the PET heat-shrinkage behavior at 85 degrees C, which is the hot-filling temperature. Sheets stretched at a higher temperature and higher speed had higher thermal stability for a wider range of draw ratios. This is because those sheets have a higher crystallinity and relaxed amorphous regions. The higher stretch speed gives the sheet a higher crystallinity with self heat generation during rapid deformation. A higher stretch temperature makes the molecular segments relaxed.