Polymer Engineering and Science, Vol.38, No.11, 1812-1823, 1998
Low density microcellular foam processing in extrusion using CO2
A continuous extrusion process for the manufacture of low-density microcellular polymers is presented. Microcellular polymers are foamed plastics characterized by a cell density greater than 10(9) cells/cm(3) and a fully grown cell size on the order of 10 mu m Previous research on continuous processing of microcellular polymers has focused on control of microcell nucleation in extrusion. This paper presents an effective means for control of cell growth to achieve a desired expansion ratio with CO2 as a blowing agent in microcellular foam processing. Also, a strategy to prevent deterioration of the cell-population density via cell coalescence during expansion is presented. Promotion of a desired volume expansion ratio and prevention of cell coalescence in microcellular foam processing were experimentally verified. By tailoring the extrusion processing parameters, microcellular HIPS foams with a cell density of 10(10) cells/cm(3) and a controlled expansion ratio in the range of 1.5 to 23 were obtained.
Keywords:STYRENE-ACRYLONITRILE COPOLYMER;TENSILE TOUGHNESS;CELLNUCLEATION;POLYCARBONATE;POLYSTYRENE;ADDITIVES;POLYMERS