Polymer Engineering and Science, Vol.40, No.6, 1429-1434, 2000
Cure kinetics and properties of epoxy/dicyanate blends
The cure behavior and properties of epoxy/dicyanate blends containing a stoichiometric amount of an amine curing agent for epoxide groups were investigated as a function of blend composition. Differential scanning calorimetry (DSC) was used to investigate the dynamic and isothermal cure behavior of the blends. The cure rate of the blend increased with increasing dicyanate content. A second order autocatalytic reaction mechanism described the cue kinetics of the blends. The kinetic parameters were determined by fitting the dynamic DSC data to the model kinetic equation. The k(10) and E-1 values were mainly affected by the change of dicyanate content. The glass transition temperature of the blend decreased with increasing dicyanate content. The thermal decomposition characteristics of the blends were investigated by thermogravimetric analysis (TGA). Dynamic mechanical analysis (DMA) and thermal mechanical analysis (TMA) were used to investigate the mechanical properties of the blends. With increasing dicyanate content, the cure rate increased but the thermal and mechanical properties of the cured blends were not improved.