An extended-solid phase, carbon dioxide phase V (CO2-V), was synthesized in a diamond anvil cell by Laser heating the molecular orthorhombic phase, carbon dioxide phase III, above 40 gigapascals and 1800 kelvin. This new material can be quenched to ambient temperature above 1 gigapascal. The vibration spectrum of CO2-V is similar to that of the quartz polymorph of silicon dioxide, indicating that it is an extended covalent solid with carbon-oxygen single bonds. This material is also optically nonlinear, generating the second harmonic of a neodymium-yttrium-lithium-fluoride Laser at a wavelength of 527 nanometers with a conversion efficiency that is near 0.1 percent.