The performance of solid oxide fuel cells, especially on the air side, degrades very rapidly when chromia forming alloys are used as interconnects in contact with electrodes. The effect of chromia forming alloys on the performance of doped LaMnO3 air electrode has been studied at the current fuel cell operating temperatures in the vicinity of 900-1000 degrees C. Interactions between a chromium-rich allay and doped LaMnO, were studied during testing of fuel cell stacks as well as in specially designed electrochemical experiments. On completion of these experiments interconnect/electrode and electrode/ electrolyte interfaces as well as interconnect, electrode and electrolyte materials were examined with scanning electron microscopy (SEM)/energy dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD) and optical microscopy. A mechanism for cell performance degradation based on these observations has been proposed.