Thermochimica Acta, Vol.236, 15-22, 1994
Thermodynamics of Associated Solutions - Prediction of Excess Molar Enthalpies of Acetone Plus Bromoform Plus Saturated-Hydrocarbon Mixtures Using a Chemical-Model
A chemical model based on mole-fraction statistics is used to predict ternary excess molar enthalpies for acetone + bromoform + saturated hydrocarbon mixtures, in which the hydrocarbon is cyclohexane, n-hexane, n-heptane, or n-decane, from binary information alone. The model used gives significantly smaller deviations between the calculated and experimental results than the chemical models proposed by Singh et al.
Keywords:THERMOCHEMICAL INVESTIGATIONS