화학공학소재연구정보센터
Thermochimica Acta, Vol.243, No.1, 79-93, 1994
A Geometric-Probabilistic Approach to Heterogeneous Chemical-Kinetics with Respect to the Ikp Ambiguity
The widely used geometric-probabilistic formalism, which is rigorous with respect to nuclei impingement simulation, is shown to be essentially ambiguous for the inverse kinetic problem (IKP) solution. This holds true for all particular models derived within its framework. The nature of this ambiguity is made explicit. A partial solution of this is suggested, by a more detailed interpretation of the scheme through its restatement in mathematical terms of tessellations.