화학공학소재연구정보센터
Thermochimica Acta, Vol.274, 173-177, 1996
On the Validity of the Steady-State Approximation in Nonisothermal Kinetics .2.
The authors discuss the steady-state approximation for variable temperature and, implicitly in time, kinetic constants, within the framework of the kinetic analysis of a sequence of two first-order consecutive reactions with an active intermediate. It is thus demonstrated that the steady-state approximation as used in isothermal kinetics may also be applied in the non-isothermal kinetics.