화학공학소재연구정보센터
Thermochimica Acta, Vol.280-281, 83-100, 1996
Diffuse Interface Model of Volume Nucleation in Glasses
A diffuse interface theory (DIT) of nucleation is applied for the crystallization of various oxide glasses showing volume nucleation. It is demonstrated that, in contrast with the classical theory which often yields "anomalous" nucleation prefactors, the DIT is consistent with the experiments. A method is outlined for distinguishing homogeneous and volumetric heterogeneous nucleation mechanisms.