Thermochimica Acta, Vol.292, No.1-2, 51-57, 1997
Excess-Enthalpies for Inorganic Liquids with Supercritical Carbon-Dioxide - Equation of State Correlations
Excess enthalpies along isotherm/isobars for binary mixtures of liquid neopentane, SnCl4, and TiCl4, in supercritical CO2 are correlated with two equations of state. Both equations use a Percus-Yevick hard-sphere repulsive pressure term added to an attractive term, and temperature dependent size parameters. One attractive term is empirical, the other is based on a square-well potential. Calculations for pure component enthalpies fit data better than molecular dynamics simulations, but the simulations better predict the excess enthalpies.