화학공학소재연구정보센터
Thin Solid Films, Vol.300, No.1-2, 218-222, 1997
Formation of Wsi-Based Ohmic Contacts to N-Type GaAs
An outcome of the indirect doping concept conceived recently in NiGe-based Ohmic contacts has led to the development of annealed WSi-based Ohmic contacts to n-type GaAs for the first time. It was concluded that simultaneous addition of a "direct doping element" of Si in WSi2.7 and an "indirect doping element (M)" such as Au, Pd, Cu, or Ag, was essential. The M(5 nm)/WSi2.7(20 nm)/W(50 nm) contacts showed Ohmic behavior after annealing with the lowest contact resistances of 0.4 Omega mm (similar to 6 x 10(-6) cm(2)). In addition, the WSi-based contacts with a small amount of Au showed good thermal stability at 400 degrees C after contact formation. Microstructural analysis of the WSI contacts with Au showed formation of beta-AuGa and WSi2 compounds, which indicates that the Ohmic behavior would be due to heavy doping of Si at the GaAs surface induced by Ga out-diffusion. The mechanism of Ohmic contact formation of the present contacts agreed very well with that of the NiGe-based Ohmic contacts.