화학공학소재연구정보센터
Transport in Porous Media, Vol.39, No.2, 131-141, 2000
Percolation cluster statistics and conductivity semi-variograms
Cluster statistics of percolation theory have been shown to generate expressions for the distribution of hydraulic conductivity values in accord with field studies. Percolation theory yields directly the smallest possible generalized resistance value, R-c, for which a continuous path through an infinite heterogeneous system can avoid all larger resistances. R-c, defines an infinite system hydraulic conductivity. Cluster statistics generate the number of clusters of resistors of a given size with a given R, for which a continuous path through the cluster can avoid resistances larger than R. The probability that a volume of size x(3) 'falls on' a particular cluster gives the probability that volume has a characteristic resistance, R. Determining the semi-variogram of the hydraulic conductivity is now elementary; it is necessary only to determine whether translation h of the center of the volume x(3) removes it from the cluster in question. If the cluster is larger than (x + h)(3), then, on the average, the same cluster resistance R will control K. Otherwise, the value of K at x + h will be uncorrelated with its value at x. The condition is then expressed as an integral related to the one, which gives the distribution of K. Then an integral over the derived distribution of K gives the variogram. Results obtained are that the variogram should be similar to either the exponential or Gaussian forms typically in use, if K is a power law function of random variables (as in Poiseuille's Law), or more closely related to the spherical approximation if K is an exponential function of random variables.