Turkish Journal of Chemistry, Vol.22, No.2, 115-122, 1998
The amido and bisalkoxo-complexes of [tri(3,5-dimethylpyrazolyl)borato]molydenum nitrosyl
In this study, the amido nitrosyl molybdenum complex, [Mo{HM(3,5-Me2C3HN2)(3)}(NO)Cl(NH2)], was prepared. This compound reacts with alocohols, yielding the bisalkoxo complexes, [Mo{HM(3,5-Me2C3HN2)(3)}(NO)(OR)(2)] (R = Me, Et, Pr-n, Bu-n). The new complexes were analyzed by IR and H-1-NMR spectroscopy.
Keywords:MOLYBDENUM MONONITROSYL COMPLEXES;NONLINEAR-OPTICAL MATERIALS;REDOX CENTERS;LIGANDS;TUNGSTEN;DERIVATIVES;CRYSTAL