Ethylene Dimerization Catalyst of Nickel Sulfate Supported on Silica-Alumina

Jong Rack Sohn; Won Cheon Park

Korean Journal of Chemical Engineering, Vol.17, No.6, 727-730, November, 2000

DOI10.1007/BF02699125 Export Citation

Ethylene Dimerization Catalyst of Nickel Sulfate Supported on Silica-Alumina

Jong Rack Sohn^†, and Won Cheon Park

Department of Industrial Chemistry, Engineering College, Kyungpook National University, Taegu 702-701, Korea

E-mail:

Catalysts containing various nickel sulfate content were prepared by dry impregnation of silica-alumina or silicagel with aqueous solution of nickel sulfate. SiO2-Al2O3 alone without NiSO4 was totally inactive for the ethylene dimerization reaction at room temperature. However, NiSO4/SiO2-Al2O3 was found to be very active even at room temperature compared with NiSO4/SiO2.

Keywords:Ethylene Dimerization;Nickel Sulfate/Silica-Alumina;Impregnation

[References]

Bonneviot L, Olivier D, Che M, J. Mol. Catal., 21, 415 (1983)
Coh BY, Hur JM, Lee HI, Korean J. Chem. Eng., 14(6), 464 (1997)
Kimura KAIH, Ozaki A, J. Catal., 18, 271 (1970)
Kim SH, Cho SM, Yoon KJ, Korean J. Chem. Eng., 14(1), 69 (1997)
Kwak C, Moon SH, Korean J. Chem. Eng., 16(5), 608 (1999)
Ozaki A, Kimura K, J. Catal., 3, 395 (1964)
Park YC, Rhee HK, Korean J. Chem. Eng., 15(4), 411 (1998)
Satsuma A, Hattori A, Mizutani K, Furuta A, Niyamoto A, Hattori T, Murakami Y, J. Phys. Chem., 93, 6052 (1988)
Sohn JR, Bae JH, Korean J. Chem. Eng., 17(1), 86 (2000)
Sohn JR, Jang HJ, Kim HW, Korean J. Chem. Eng., 7(1), 7 (1990)
Sohn JR, Kim HJ, J. Catal., 101, 428 (1986)
Sohn JR, Kim NW, Kim JT, Korean J. Chem. Eng., 4(1), 1 (1987)
Sohn JR, Lee SY, Appl. Catal. A: Gen., 164(1-2), 127 (1997)
Sohn JR, Ozaki A, J. Catal., 61, 29 (1980)
Sohn JR, Shin DC, J. Catal., 160(2), 314 (1996)
Tanabe K, Misono M, Ono H, "New Solid Acids and Bases," Chap 1, Elsevier, New York (1989)
Tanabe K, "Solid Acids and Bases," Chap 4, Kodansha, Tokyo (1970)
Urabe K, Koga M, Izumi Y, J. Chem. Soc.-Chem. Commun., 807 (1989)
Wendt G, Hentschel D, Finster J, Schollner R, J. Chem. Soc.-Faraday Trans., 79, 2013 (1983)
Yamaguchi T, Appl. Catal., 61, 1 (1990)

[Referenced By]

[1] Bonneviot L, Olivier D, Che M, J. Mol. Catal., 21, 415 (1983)

[2] Coh BY, Hur JM, Lee HI, Korean J. Chem. Eng., 14(6), 464 (1997)

[3] Kimura KAIH, Ozaki A, J. Catal., 18, 271 (1970)

[4] Kim SH, Cho SM, Yoon KJ, Korean J. Chem. Eng., 14(1), 69 (1997)

[5] Kwak C, Moon SH, Korean J. Chem. Eng., 16(5), 608 (1999)

[6] Ozaki A, Kimura K, J. Catal., 3, 395 (1964)

[7] Park YC, Rhee HK, Korean J. Chem. Eng., 15(4), 411 (1998)

[8] Satsuma A, Hattori A, Mizutani K, Furuta A, Niyamoto A, Hattori T, Murakami Y, J. Phys. Chem., 93, 6052 (1988)

[9] Sohn JR, Bae JH, Korean J. Chem. Eng., 17(1), 86 (2000)

[10] Sohn JR, Jang HJ, Kim HW, Korean J. Chem. Eng., 7(1), 7 (1990)

[11] Sohn JR, Kim HJ, J. Catal., 101, 428 (1986)

[12] Sohn JR, Kim NW, Kim JT, Korean J. Chem. Eng., 4(1), 1 (1987)

[13] Sohn JR, Lee SY, Appl. Catal. A: Gen., 164(1-2), 127 (1997)

[14] Sohn JR, Ozaki A, J. Catal., 61, 29 (1980)

[15] Sohn JR, Shin DC, J. Catal., 160(2), 314 (1996)

[16] Tanabe K, Misono M, Ono H, "New Solid Acids and Bases," Chap 1, Elsevier, New York (1989)

[17] Tanabe K, "Solid Acids and Bases," Chap 4, Kodansha, Tokyo (1970)

[18] Urabe K, Koga M, Izumi Y, J. Chem. Soc.-Chem. Commun., 807 (1989)

[19] Wendt G, Hentschel D, Finster J, Schollner R, J. Chem. Soc.-Faraday Trans., 79, 2013 (1983)

[20] Yamaguchi T, Appl. Catal., 61, 1 (1990)