Korea Polymer Journal, Vol.6, No.2, 193-199, June, 1998
Synthesis and Photoinduced Birefringence of Azobenzene-containing Polymaleimides
Azobenzene polymers having succinimide backbone structures were prepared and photoinduced birefringence oi the polymers was investigated. Three functional maleimide monomers, N-4-[4-(phenylazo)phenylcarbamoyl]phenylmaleimide (1), N-4-[4-(4-nitrophenylazo)phenylcarbamoyl]phenylmaleimide (2), 2-[N-ethyl-4-(4-nitrophenylazo)phenylamino]ethyl maleimidobenzoate (3) were synthesized by reacting maleimidobenzoyl chloride with three azobenzene dyes, p-phenylazoaniline, disperse orange 3, disperse red 1 (DR1), respectively. Radical copolymerizations of the monomers 1, 2, and 3 with styrene, isobutyl vinyl ether, or methyl methacrylate were carried out to obtain soluble azobenzene-containing polymaleimides. The styrenic copolymers P1, P2, and P3 have high glass transition temperatures of 200, 175 and 150 degrees C, respectively. A different azo polymer, P4 was obtained by copolymerization of N-phenylmaleimide (PMI) with 3-isopropenyi-alpha,alpha-dimethylbenzyl isocyanate (IMSt) followed by a postreaction of the isocyanate prepolymer P(PMI/IMSt) with DR1. Upon irradiation of the amorphous films with linearly polarized light P3 and P4 rendered birefringence by induced optical anisotropy.
- Xie S, Natansohn A, Rochon P, Chem. Mater., 5, 403 (1993)
-
Chang JY, Kim TJ, Han MJ, Choi DH, Kim N, Polymer, 38(18), 4651 (1997)
- Natansohn A, Rochon P, Gosselin J, Xie S, Macromolecules, 25, 2268 (1992)
- Ahn KD, Polymeric Materials Encyclopedia, CRC Press, Boca Raton, vol. 4, pp. 2621 (1996)
- Barrett C, Natansohn A, Rochon P, Chem. Mater., 7, 899 (1995)
-
Ho MS, Natansohn A, Rochon P, Macromolecules, 29(1), 44 (1996)
-
Mcculloch IA, Macromolecules, 27(7), 1697 (1994)
- Kang CS, Winkelhahn HJ, Schulze M, Neher D, Wegner G, Chem. Mater., 6, 2159 (1994)
-
Lee SY, Lee H, Cheong CM, Kim JM, Ahn KD, Polym. Bull., 40(1), 1 (1998)
- Oishi T, Fujimoto M, J. Polym. Sci. A: Polym. Chem., 30, 1821 (1992)
- Strohriegl P, Macromol. Chem., 194, 363 (1993)
- Turner SR, Anderson C, Kolterman KM, J. Polym. Sci. C: Polym. Lett., 27, 253 (1989)