Korean Journal of Chemical Engineering, Vol.18, No.3, 303-307, May, 2001
Metal Hydride Characteristics by Zr and Ti
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Hydrogen absorption experiments were carried out using zirconium (Zr) and titanium (Ti) in the form of a metal sponge, strip and rod to investigate the metal hydride characteristics. The Zr and Ti sponges showed a high hydrogen absorption capacity despite a low reaction temperature. The H/M, which indicates the capacity of hydrogen absorption, was measured at 2.0 for the Zr/Ti sponge at 25 ℃. In the case of the Zr/Ti strip and rod, however, the hydrogen absorption capacity was very low at 25 ℃. The capacity of hydrogen absorption increased with an increase in the reaction temperature. When the Ti strip was not activated, the H/M ratio was measured at 0.58. When the Ti strip was once and twice activated at 800 ℃ for 1 hour, the H/M ratio increased to 1.6 and 1.83, respectively. The hydrogen absorption capacity decreased with the increment of concentration of helium in hydrogen due to a blanketing effect of metal surface by the helium. A pulverizing phenomenon during the metal hydriding was observed in both the Zr/Ti strip and the Zr/Ti rod. However, this pulverizing phenomenon was not observed in the Zr/Ti sponges because of their high surface area.
- Cox KE, Williamson KD, "Hydrogen and Its Technology," Volume II, CRC Press, Cleveland (1977)
- Hwang KS, Gong SY, Lee WK, Korean J. Chem. Eng., 8(3), 148 (1991)
- Holtslander WJ, Yaraskavitch JM, "Tritium Immobilization and Packaging Using Metal Hydrides," AECL-7151 (1981)
- Holtslander WJ, Miller JM, "Immonilization and Packaging of Recovered Tritium," AECL-7757 (1982)
- Ishiyama S, Fukaya K, Eto M, Miya N, J. Nucl. Sci. Technol., 37(2), 144 (2000)
- Kabutomori T, Wakisaka Y, Kawamura H, J. Nucl. Mater., 258(263), 481 (1998)
- Lee HI, White JM, Korean J. Chem. Eng., 1(2), 129 (1984)
- Lee HS, "Hydrogen Isotope Storage in Zircaloy Scrap," KAERI/RR-1928 (1998)
- Reilly JJ, Wiswall RH, "Hydrogen Storage and Purification Systems," BNL-21322 (1976)