Applied Catalysis A: General, Vol.205, No.1-2, 71-77, 2001
Kinetic behavior of hydrogenation of aromatics in diesel fuel over silica-alumina-supported bimetallic Pt-Pd catalyst
The kinetics and long-term stability test of the aromatic hydrogenation of diesel fuel were studied on SiO2-Al2O3 supported bimetallic Pt-Pd catalyst. The tests on the influence of operating parameters and kinetics studies were carried out using Pt (0.5 wt.%)-Pd (1.0 wt.%)/SiO2-Al2O3. which provided the highest catalytic activity in a previous paper [Applied Catalysis A: General, 192 (2000) 253] with hydrotreated light cycle oil (LCO)/straight-run light gas oil (SRLGO) feedstocks containing 30 vol.% aromatics/100 wppm sulfur and 34 vol.% aromatics/420 wppm sulfur under numerous conditions. The results on this catalyst obtained at different LHSV showed an excellent fit to first-order kinetics. The apparent activation energy was determined to be 92 kJ/mol. Long-term stability test demonstrated the excellent stability of this catalyst. The products during the long-term stability test are of good quality, with the upgraded color, the increased cetane index, and sufficiently decreased sulfur content.