화학공학소재연구정보센터
Journal of Applied Polymer Science, Vol.79, No.9, 1556-1562, 2001
Catalytic aspect of chemical modifications of polymers by transesterification: NMR study with model compounds
The catalytic activity of different compounds (dibutyl tin oxide, titanium tetrabutoxide, zirconium tetraethoxide, and para-toluenesulfonic acid) for transesterification reactions between polymers was studied. This study was carried out on three different reactions: between two model compounds (methyl benzoate and octyl acetate), between a polymer and a model compound (ethylene-vinyl acetate copolymer and methyl benzoate), and for crosslinking of ethylene-vinyl acetate copolymer with dimethyl terephthalate. For these three reactions dibutyl tin oxide presented the higher catalytic activity.